02 Hydrogen Atom Flashcards

(34 cards)

1
Q

What is a line spectrum

A

a spectrum showing only certain colors of light

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2
Q

spectrum for white light

A

contains all frequencies of visible light

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3
Q

what is a lazer

A

monocromatic spectrum

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4
Q

absorption

A

ground state -> excited state

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5
Q

emission

A

excited state -> ground state

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6
Q

electronic transition

A

an electron within an atom is jumping from one allowed state to another and emitting a photon in the form of electromagnetic radiation

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7
Q

as n decreases…

A

distance decreases, attraction increases and energy gets lower or more negative

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8
Q

is attractive energy more negative or more positive

A

more negative

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9
Q

electron transitions from a higher (less negative) energy orbit (larger n) to a lower (more negative) orbit result in…

A

the emission of photons with matching energies

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10
Q

absorption of photons of the appropriate energy…

A

promotes electrons from a lower orbit to a higher one

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11
Q

at n = infinity, energy is

A

zero

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12
Q

what is ionization

A

atom gaining or losing electrons to form ions

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13
Q

energy will be negative when we have _______ and indicates a ________

A

an attractive interaction
a release of energy

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14
Q

closer to the nucleus =
higher or lower energy

A

lower energy
- due to the significant attractive forces

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15
Q

both disance and energy are…

A

quantized! meaning that only specific values are possible

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16
Q

as n increases…

A

the radius increases
the energy will increase and will become less negative
the energy levels get closer and closer together

17
Q

what is electron density

A

the probability of an electron residing in a given tiny volume of space

18
Q

what is ionization energy

A

energy needed to remove an electron

19
Q

what does being quantized mean

A

can only have specific values

20
Q

what is an orbital

A

a 3d region of space that can hold an electron

21
Q

where is electron density the highest

A

around the nucleus, tapers off as you get farther

22
Q

what are quantum numbers

A

numbers required to describe arrangement of electrons in an atom

23
Q

Principal quantum number (n)

A

tells us the shell
indicates energy and distance from the nucleus
integer ranging from 1 to infinity
(city)

24
Q

angular momentum quantum number (l)

A

integer ranging from 0 to n-1

25
what letter is l = 0 and what shape does this correspond to
s (sphere)
26
what letter and shape does l = 1 correspond to
p and ‘dumbells’
27
what letter and shape does l = 2 correspond to
d and ‘clover’ or ‘dumbell donut’
28
what letter and shape does l = 3 correspond too
f and the shape is too complicated to define
29
what is magnetic quantum number (ml)
integer ranging from -l … 0 … +l the number of possible ml gives the number of orbitals in the subshell describes spatial oreintation
30
what does degenerate mean
having an equal energy
31
what is boundary surface
the surface within which there is a specified probability (often 90%) that an electron will be found
32
what is energy splitting due to
it is due to electron-electron repulsion and the idea of effective nuclear charge
33
what are the only two values that the magnetic momentum of an electron can be
+1/2 or -1/2
34
n
o