Thermochemistry Flashcards

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1
Q

What is thermochemistry

A

The study of relations between CHEMICAL REACTIONS and ENERGY

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2
Q

What is MATTER

A

Anything having a MASS and occupying SPACE

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3
Q

How is MATTER classified

A

by its STATE (liquid, solid, gas) and its COMPOSITION (heterogeneous mixture, element, compound, etc.)

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4
Q

What is ENERGY

A

WORK of anything that can be produced by or converted into WORK

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5
Q

What are the two classifications of ENERGY

A

POTENTIAL and KINETIC

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6
Q

What is the formula for POTENTIAL ENERGY?

A

E(p) = mg(delta)h

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7
Q

What is the formula for KINETIC ENERGY?

A

E(k) = [mv^2]/2

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8
Q

What do E, v, m, g and h stand for?

A

E= energy, v=, m=, g=, h=.

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9
Q

How many JOULES is one CALORIE?

A

1CALORIE = 4.184 JOULES

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10
Q

What is the formula for ONE JOULE

A

kg*m^2/s^2

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11
Q

What are the forms of POTENTIAL ENERGY? (4)

A

Gravitational, Chemical, Nuclear, Electrical

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12
Q

What are the forms of KINETIC ENERGY? (2)

A

Motion, heat

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13
Q

What is the relation between a SYSTEM, a BOUNDARY and SURROUNDINGS?

A

the SYSTEM is limited by the BOUNDARY. Outside of the BOUNDARY, there are SURROUNDINGS.

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14
Q

What is an OPEN SYSTEM?

A

A SYSTEM that may exchange ENERGY and MATTER with SURROUNDINGS

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15
Q

What is a CLOSED SYSTEM?

A

A SYSTEM that may NOT exchange MATTER ONLY with SURROUNDINGS

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16
Q

What is an ADIABATIC SYSTEM?

A

A SYSTEM that may not exchange HEAT ONLY with SURROUNDINGS

17
Q

What is an ISOLATED SYSTEM?

A

A SYSTEM that an not exchange HEAT nor MATTER with surroundings.

18
Q

What is an ENDOTHERMIC PROCESS?

A

When there is ABSORPTION of ENERGY

19
Q

What is an EXOTHERMIC PROCESS?

A

When there is a RELEASE of ENERGY

20
Q

What is the formula for ENTHALPY?

A

(Delta)H = q(p)

21
Q

What do q and p stand for?

A

q = enthalpy (J/mol or kJ/mol) and p = constant pressure

22
Q

What INSTRUMENT is used to measure HEAT?

A

A CALORIMETER

23
Q

What is CALORIMETRY

A

The measurement of HEAT FLOW

24
Q

What is the sum of q’s always equal to?

A

Zero.

25
Q

What system is a CALORIMETER and its CONTENTS?

A

An ADIABATIC SYSTEM

26
Q

What is HEAT CAPACITY?

A

The amount of HEAT required to raise TEMPERATURE of a substance by 1K or 1C

27
Q

What is the formula for HEAT CAPACITY?

A

C = q/(delta)T

28
Q

What is the difference between HEAT CAPACITY and SPECIFIC HEAT CAPACITY?

A

SPECIFIC HEAT CAPACITY is for a SPECIFIC AMOUNT (g) of substance while HEAT CAPACITY is for an OBJECT

29
Q

What is the formula for SPECIFIC HEAT CAPACITY?

A

C = q/w(delta)T, w meaning weight (g)

30
Q

What is the standard enthalpy of formation of a compound?

A

The ENTHALPY CHANGE after the formation of 1 MOLE at 25C and 1 ATM from the elements in their standard state.

31
Q

What is the law of Lavoisier and Laplace

A

If we switch the sides of an equation, the enthalpy becomes the opposite sign.

32
Q

What is the enthalpy change for a chemical reaction ?

A

q = n(delta)h, n meaning number of moles.

33
Q

What is the delta H of any element equal to ?

A

Zero.