Hydrocarbons Flashcards

1
Q

Size of C—C bond and C—H bond

A

154pm and 112pm

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2
Q

_________ act as catalysts at room temperature whereas ______ is required at higher temperature and pressure
(Hydrogenation)

A

Palladium and platinum

Nickel

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3
Q

In Kolbe’s electrolysis, methyl free radical is produced at which electrode

A

Anode!

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4
Q

Catalysts used for methanol, methanal and Ethanoic acid?

A

Cu
Mo2O3
(CH3COO)2Mn

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5
Q

Tertiary alkanes on vigorous oxidation

A

Give alcohols

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6
Q

Catalyst for isomerization

A

AlCl3/HCl

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7
Q

Pyrolysis is a __________ reaction

A

Free radical

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8
Q

Torsional strain for ethane?

A

12.5kJ/mol

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9
Q

What is partially deactivated palladized charcoal? What is it deactivated with?

A

Lindlar’s Catalyst

Sulphur compounds or quinoline

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10
Q

Which halogen addition reaction is not seen in normal conditions (alkene)

A

Iodine

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11
Q

dil KMnO4 oxidates alkenes to?

acidic KMnO4 or K2Cr2O7 oxidizes it into?

A

Glycols

Carbonyl or carboxyl

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12
Q

Alkynes addition:
I. Halogens
II. Hydrogen halides

A

I. Vic dihalide

II. Gem dihalide

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13
Q

Which year Wohler synthesized urea

A

1828

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14
Q

acetic acid synthesized by

A

Kolbe

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15
Q

methane synthesized by

A

Berthelot

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16
Q

remember tetrahydrofuran

A

pentagon with O at apex

remember thiophene too