1.2 Flashcards

1
Q

What is an orbital

A

A place where there’s high probability of finding an electron

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2
Q

What is the maximum amount of electrons in each sub shell?

A

s-2
p-6
d-10

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3
Q

What is the rule regarding 4s?

A

electrons enter 4s before 3d, and leave 4s before 3d

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4
Q

What are the exceptions of the 4s rule?

A

Chromium and Copper

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5
Q

What is the first molar ionisation energy?

A

The energy needed to remove one mole of outer electrons from one mole of gaseous atoms

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6
Q

What are the 3 factors that affect ionisation energy?

A

-Distance from nucleus
-Nuclear charge (proton number)
-Inner electron shielding

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7
Q

Whats the trend for ionisation energy down a group?

A

Going down, decreases as there is more shielding and less effective nuclear force

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8
Q

What is the trend for ionisation energy going across a period?

A

Generally increases, as nuclear charge increases

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9
Q

Explain the group 2 to 3 discontinuity (Be, B)

A

-Be outermost electron is on s shell
-B outermost electron is p shell
-B outermost electron is easier to remove because it’s further from nucleus

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10
Q

Explain the group 5 to 6 discontinuity (N, O)

A

-Both have the most outermost electron in the p shell, on same energy level
-Because of repulsion, its easier to remove one of Oxygens paired electrons

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11
Q

Explain Alpha decay

A
  • Nucleus emits 2 protons and 2 neutrons
    -Atomic number goes down by 2
    -Atomic mass goes down by 4
    -Can be stopped by a few cm of air or a piece of paper
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12
Q

Explain Beta- decay

A

-An electron is emitted from the nucleus
-Neutron turns into proton
-Atomic number increases
-Mass number stays the same
-Stopped by 5mm of Al or a few metres of air

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13
Q

Explain Beta+ decay (positron emission)

A

-Proton turns into neutron and a positron
-Positron is emitted from nucleus
-Mass number stays same
-Atomic number decreases

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14
Q

Explain electron capture

A

-Occurs in proton rich atoms, outer shell electron is drawn into nucleus and combines with proton, making a neutron
-Mass number remains same
-Atom number drops by one

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15
Q

Explain gamma emission

A

-No particle is emitted and nucleus does not change
-Can be stopped by 10cm of lead, 1m of concrete, or a few km of air

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16
Q

How do alpha particles act in an electric field?

A

-They are positive, heavy, slow moving
-Attracted to negative plate (cathode)

17
Q

How do Beta- particles act in an electric field?

A

-Light and fast moving
-Attracted to positive plate (anode)

18
Q

How does gamma radiation act in an electric field?

A

Uncharged, therefore unaffected

19
Q

What is the relationship between frequency and energy?

A

Directly proportional

20
Q

In the balmer series, what energy level do photons relax to?

A

the second

21
Q

What are the two equations for energy change?

A

E=hf
E= hc/lambda

22
Q

What energy levels do photons relax to in the Lyman series?

A

The first

23
Q

What is the convergence limit?

A

The frequency at which the difference in frequency between successive lines is zero