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MCAT Review > Organic Chemistry > Flashcards

Organic Chemistry Flashcards

1
Q

Methyl Polar Protic

A

Sn2

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2
Q

Primary Polar Protic

A

Sn2

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3
Q

Secondary Polar Protic

A

Sn1/E1

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4
Q

Tertiary Polar Protic

A

Sn1/E1

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5
Q

Methyl Polar Aprotic

A

Sn2

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6
Q

Primary Polar Aprotic

A

Sn2

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7
Q

Secondary Polar Aprotic

A

Sn2

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8
Q

Tertiary Polar Aprotic

A

Sn1/E1

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9
Q

Methyl Strong Small Base

A

Sn2

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10
Q

Primary Strong Small Base

A

Sn2

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11
Q

Secondary Strong Small Base

A

E2

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12
Q

Tertiary Strong Small Base

A

E2

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13
Q

Methyl Strong Bulky Base

A

Sn2

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14
Q

Primary Strong Bulky Base

A

E2

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15
Q

Secondary Strong Bulky Base

A

E2

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16
Q

Tertiary Strong Bulky Base

A

E2

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17
Q

Polar Protic Solvents

A

Acetic Acid, H2O, ROH, NH3

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18
Q

Polar Aprotic Solvents

A

DMF, DMSO, Acetone, Ethyl Acetate

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19
Q

PCC

A

Oxidizes 1° alcohols to aldehydes
Oxidizes 2° alcohols to keytones

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20
Q

KMnO4

A

Oxidizes 1° alcohols to carboxylic acids
Oxidizes 2° alcohols to keytones

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21
Q

H2Cr2O4

A

Oxidizes 1° alcohols to carboxylic acids
Oxidizes 2° alcohols to keytones

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22
Q

NaBH4

A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols

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23
Q

LiAlH4

A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols
Reduces carboxylic acids to 1° alcohols
Reduces esters to 2° alcohols

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24
Q

LiAlH4

A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols
Reduces carboxylic acids to 1° alcohols
Reduces esters to 2° alcohols

25
Q

N-H IR Peak

A

Sharp 3300

26
Q

O-H IR Peak

A

Broad 300-3300

27
Q

Triple Bond CO/CN

A

Medium 1900-2200

28
Q

CO Double Bond IR

A

Sharp 1750

29
Q

CC Double Bond

A

Weak 1600-1680

30
Q

Formyl Group

A
31
Q

Formaldehyde

A
32
Q

Formic Acid

A
33
Q

Acetyl group

A
34
Q

Acetaldehyde

A
35
Q

Acetic Acid

A
36
Q

Acetone

A
37
Q

Acetylacetone

A
38
Q

Acetophenone

A
39
Q

Benzyl Group

A
40
Q

Benzaldehyde

A
41
Q

Benzoic Acid

A
42
Q

Benzoin

A
43
Q

Styrene

A
44
Q

Acryl Group

A
45
Q

Acrolein

A
46
Q

Acrylic Acid

A
47
Q

Carboxyl Group

A
48
Q

Carboxylate Ion

A
49
Q

Carbonate Ion

A
50
Q

Carbonic Acid

A
51
Q

Cation-Exchange Chromatography

A

Has negative charged beads and attracts cations.

52
Q

Affinity Chromatography

A

Uses a bound receptor or ligand and an eluent with free ligand or a receptor for the protein of interest.

Histidine Tags are a good example.

53
Q

Pyrrole

A
54
Q

Short Chain Fatty Acids

A
55
Q

Amide

A
56
Q

Amine

A
57
Q

Imine

A
58
Q

Enamine

A

MCAT Review (9 decks)

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