7.1-7.6 Flashcards

1
Q

equilibrium

A

when a reaction and its reverse reaction occur at the same rate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

how to tell when equilibrium is reached on concentration graph…

A

when concentrations are both constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

how to tell when equilibrium is reached on rate graph…

A

when rates are the same

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

once equilibrium is reached, the amount of each reaction and product…

A

remains constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

favored

A

one direction in an equilibrium equation is favored

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

if the forward reaction is exothermic…

A

the reaction will be favored (smaller Ea)
there will be more products in equilibrium mixture
opposite is true for endothermic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

in endothermic equilibrium there are more

A

reactants

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

the smaller Ea is

A

favored

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

catalysts in equilbirium

A

don’t change the amount of reactants/products just makes easier

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

equilibrium constant with molarity

A

[products]^coefficient/[reactants]^coefficient

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

equilibrium constant with pressure

A

(products)^coefficient/(reactants)^coefficient

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

if k>1

A

reaction favors products, exothermic
reactants to products

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

if k<1

A

reaction favors reactants, endothermic
products to reactants

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

homogenous equilibrium

A

all reactants and products in the same state

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

use the value of __ for the concentration of a pure substance

A

1
such as solid/liquid water
(eliminate them from expression!)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

when finding Kc eliminate…

A

(liquid) water and solids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

ICE table

A

Initial, change, equilibrium

18
Q

I

A

reactants: given in problem, mol/L
products: 0

19
Q

E

A

reactants: use found change value
products: given

20
Q

C

A

use given value to find rate for product, use coefficients to find it for the rest
positive for products, negative for reactants

21
Q

reactant quotient Q

A

like Kc but for current conditions
to find it, sub initial concentrations of reactants and products into the equilibrium expression

22
Q

Q vs K

A

nature wants Q=K(eq)
if Q<K>K proceed to reactants</K>

23
Q

equilibrium constant of a reaction in the reverse reaction..

A

reciprocal of equilibrium constant of forward reaction

24
Q

if you multiply reaction constant

A

raise the constant to that power

25
Q

K3=

A

K1*K2

26
Q

if you flip an equation

A

take reciprocal of K

27
Q

to use solver feature

A

enter equation equal to zero
go over x, put 0, alpha enter

28
Q

analyzing diagrams

A

using balanced equation can find q for each and decide it compared to k

29
Q

adding a substance

A

shifts away from substance

30
Q

removing a substance

A

shifts toward substance

31
Q

change in temperature

A

heat is like an added substance/product, treat it as such

32
Q

change in volume or pressure

A

higher volume/lower pressure favors the side of the equation with more moles (and vice versa)

33
Q

p and v are

A

inversely related

34
Q

bigger solubility number

A

more soluble

35
Q

solubility

A

the quantity of a substance that dissolves t form a saturated solution

36
Q

increased temperature vs. solubility

A

more soluble bc more and better interactions

37
Q

common ion effect

A

if present solubility of the salt will decrease (less room)

38
Q

unsaturated

A

hasn’t reached equilibrium yet
not everyting dissolved

39
Q

saturated

A

max dissolved
at equilibrium

40
Q

will a precipitate form

A

Q<K>K precipitate</K>

41
Q

solubility

A

all Na, K, ammonium (NH4), and nitrate salts (NO3)are soluble in water