15A.3 Flashcards

1
Q

what does bimolecular mechanism

A

a mechanism in which two species are reacting in the rate determining step

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2
Q

in transition state the sign goes

A

on the outside

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3
Q

in Sn2 what happens after the transition state

A

the arrangements of the groups that remain attached to the central atom has been inverted

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4
Q

in Sn2 the optical activity of the product are reactant would be

A

opposite to each other (because of the inversion) so if the reactant is laevoratatory then the product is dextrorotatory

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5
Q

how can we find out if the mechanism that occurred is Sn2

A

by seeing if the optical activity of the product and the reactant are opposite to each other

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6
Q

what is unimolecular mechanism

A

a mechanism in which only one species is reacting in the rate-determining step

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7
Q

why is a racemic solution formed during Sn1

A

because it occurs in two steps where the first step forms is carbocation with a planar shape, which means when the negative OH comes to attack it has a 50% chance to attack on each side so two enantiomers with the same ratio form making a racemic solution

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8
Q

how can we find out if the reaction has occurred through Sn1

A

by measuring the optical activity of the product and reactant where if the reactant has optical activity and the product doesn’t that means its Sn1

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