1.6 Chemical Equilibria Flashcards
(10 cards)
Key features of a dynamic equilibrium
- Rate of forwards reaction = rate of backwards reaction
- Concentration of reactants and products is constant
If an equilibrium lies to the left, what has a higher concentration at equilibrium?
Reactants OR products
Reactants
If an equilibrium lies to the right, what has a higher concentration at equilibrium?
Reactants OR products
Products
Le Chatelier’s Principle
If a closed system in dynamic equilibrium is subjected to a change, the position of equilibrium will move in the direction that opposes that change
Conditions for the Haber process
- 200atm
- 400-450°C
- Iron catalyst
Kc
- Equilibrium constant (in terms of concentrations)
- Shows the composition of a mixture at equilibrium
Kc equation
Kc = ([P1]ᵖ¹[P2]ᵖ²) / ([R1]ʳ¹[R2]ʳ²)
[R] - reactant conc
[P] - product conc
r and p - stoichiometric coefficients
What variable can alter Kc?
Temperature
Concentrations if: Kc «_space;1
[Reactants] > [Products]
(Equilibrium to the left)
Concentrations if: Kc»_space; 1
[Products] > [Reactants]
(Equilibrium to the right)