3.7 Optical Isomerism Flashcards

(8 cards)

1
Q

Optical isomers

A

Non-superimposable mirror images

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Requirements for optical isomers

A

Carbon atom with four different atoms/groups bonded to it

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Name for the C atom at the center of an optical isomer

A

Chiral carbon (asymetrical carbon)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Name for optical isomers

A

Enantiomers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Effect of isomers on plane polarised light

A

They rotate plane polarised light by the same amount but in opposite directions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Racemic mixture

A

A mixture of equal amounts of the two enantiomers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Will a racemic mixture rotate plane polarised light

A

No - The two enantiomers will cancel each other out as they are present in equal quantities

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What causes a mixture to be racemic?

A

The shape of the reactant / intermediate, which has an equal probability of reacting in two different places

How well did you know this?
1
Not at all
2
3
4
5
Perfectly