2C Main Group Elements Flashcards

(61 cards)

1
Q

Most abundant elements in life

A

Oxygen, carbon, hydrogen, nitrogen, calcium, phosphorus

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2
Q

Most abundant elements on earth

A

Oxygen, silicon, aluminum

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3
Q

Most abundant elements in universe

A

Hydrogen, helium, oxygen

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4
Q

Protium composition

A

Hydrogen with one e one p

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5
Q

Deuterium composition

A

Hydrogen with one e one p one n

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6
Q

Tritium composition

A

Hydrogen with one e one p two n

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7
Q

Use for alkali metals

A

Reducing reagents, drying reagents

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8
Q

What alkali metal can react with nitrogen?

A

Lithium because it’s the only one hard enough

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9
Q

Where are the triels

A

Boron group

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10
Q

Where are the tetrels

A

Carbon group

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11
Q

A state is metastable if

A

It exists without observable change even though it is thermodynamically unstable with respect to another state

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12
Q

A group of MOs where the energy different between are so small that it behaves as continuous

A

Band

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13
Q

Occurs when there is a significant energy difference between two bands

A

Band gap

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14
Q

Incident photons raise electrons from valence band to conduction band

A

Photovoltaic effect

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15
Q

A material behaves as a semiconductor without addition of a dopant

A

Intrinsic semiconductor

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16
Q

Semiconductor that requires a dopant

A

Extrinsic semiconductor

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17
Q

Dopant

A

An impurity introduced in minute amounts to enhance electrical conductivity

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18
Q

Holes introduced above the energy levels of the valence band

A

P type

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19
Q

Extra electrons introduced below the energy levels of the conduction band

A

N type

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20
Q

Closo cluster

A

Closed

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21
Q

Nido cluster

A

One vertex missing

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22
Q

Arachno cluster

A

Two vertices missing

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23
Q

Where are the pnictogens

A

Nitrogen group

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24
Q

Composition of air

A

Mainly nitrogen, some oxygen, then other gases

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25
Chemiluminsecent reaction
Reaction accompanied by the emission of light
26
Accepted order of basicity of phosphines
Cy > Et > Me > Ph > OMe > OPh > Cl > F
27
Where are the Chalcogens
Oxygen group
28
Where are the halogens
Fluorine group
29
Where are the noble gases
Helium group
30
Hypochlorite
ClO-
31
Oxidation number ClO-
+1
32
Point group ClO-
C infinity v
33
ClO- shape
Linear
34
ClO- is a good…
Oxidizing agent
35
Oxidation number ClO2-
+3
36
Chlorite
ClO2-
37
Oxidation number ClO3-
+5
38
Chlorate
ClO3-
39
Oxidation number ClO4-
+7
40
Perchlorate
ClO4-
41
Chlorite point group
C2v
42
Chlorate point group
C3v
43
Perchlorate point group
Td
44
Chlorite shape
Angular
45
Chlorite is a strong
Oxidizing agent
46
Which chlorine oxoanion disproportionates
Chlorite
47
Which chlorine oxoanion is a very weak ligand
Perchlorate
48
Chlorate shape
Pyrimidal
49
Perchlorate shape
Tetrahedral
50
seebeck effect
power generation mode
51
heat source like a lightbulb
seebeck effect
52
peltier effect
refrigeration mode
53
cooling side like a battery
peltier effect
54
positive ΔH favors which direction
left to right
55
positive ΔH requires or releases energy?
requires energy to be put in
56
Lewis basicity and electron withdrawing groups
more electron withdrawing groups = less basic
57
NX3 is always a
lewis base
58
relationship between bond order and bond length
higher BO = shorter length
59
common electron donors
N P O S F Cl
60
common electron acceptors
B Al Si C
61
Most common intrinsic semiconductors
Ge and Si