3.9 Carboxylic Acids And Derivatives Flashcards

(34 cards)

1
Q

Why is the COOH group very soluble in water but doesn’t dissolve

A

Very soluble due to hydrogen bondung, hydrocarbon chain is non-polar, hence doesn’t dissolve in water
Shorter chains dissolve easier than longer chains

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2
Q

How do you name esters and where do they form from

A
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3
Q

Uses of esters

A

Perfumes
Flavorings
Solvents
Plasticers

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4
Q

How can an ester be hydrolysed

A
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5
Q

Draw mechanism of ethyl chloride reacting with alcohol
State reagents
Name of mechanism
State conditions

A

Alcohol : reagent
Conditions : room temperature

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6
Q

Draw reaction when ethanoicanydride reacts with alcohol
State reagents
Conditions

A
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7
Q

Everything you need to know to make aspirin

A
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8
Q
A
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9
Q

Ammonium ethanoate

A
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10
Q

Mr needed from Q1.1

A

H2A represents carboxylic acid. Because it is a dicarboxylic acid, two sodium hydroxides needed to neutralise it, hence there are two moles of it

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11
Q
A
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12
Q
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13
Q
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14
Q
A

As the double bond is Z, it means it comes off the same side

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15
Q
A
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16
Q

How to detect if an ester is formed

A

Sweet smelling ester forms

17
Q

Hazard of concentrated phosphoric acid

A

It is corrosive
All concentrated acids are

21
Q

Uses of esters

A
  • sweet smelling compounds
  • used as plasticisers for polymers
  • used as solvents for polar organic substances
22
Q

Uses of glycerol

A

Glycerol (propane-1,2,3-triol) forms hydrogen bonds very easily and is readily soluble in water. It is used in cosmetics, food and in glues

23
Q

What can vegetable oils and animal fats be hydrolysed to

A

soap, glycerol, and long chain carboyxlic

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Why is chloroethanoic acid a stronger acid than ethanoic acid
Chlorine is an electron withdrawing group, it has a negative inductive effect Weakens the O-H bond It increases polarity of the O-H bond
29
Decrease in volume is 4cm^3 and mass of propanone is 0.146g
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