3rd LE Flashcards

1
Q

The calorimeter is a device used to measure * that accompany a physical or a chemical process.

A

heat changes

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2
Q

The * measured from a process conducted under * is referred to as enthalpy,

A

heat, constant pressure

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3
Q

Retention factor: * parameter
B. Basis of separation: *
C. Stationary phase: *
D. Type of system: *

A

qualitative
Polarity
water adsorbed in the chromatographic paper
Close

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4
Q

Chromatography is technique used to separate components of a mixture based on differences in *

A

intermolecular forces of attraction

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5
Q

Paper chromatography is a chromatographic technique where the stationary phase is the * while the mobile phase is the * which can either be polar or nonpolar.

A

water bound to the cellulose of the paper

solvent

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6
Q

Given a specific stationary and mobile phase, a component will always have the * retention factor (Rf). The retention factor is defined as the * which is retained in the *

A

same
fraction of a component
mobile phase

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7
Q

endothermic (ΔHsoln = +),
exothermic (ΔHsoln = -)
* (ΔHsoln = 0).
This value will be dependent on the relative strengths of the * between like and unlike particles

A

athermic

interparticle forces of attraction

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8
Q

Stronger forces of attraction between unlike particles result in an overall * in the volume of solution; otherwise an overall * in the volume of solution is observed.

A

contraction

expansion

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9
Q

Glycerol – *

Naphthalene – *

A

polar

nonpolar

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10
Q

chromatography (based on differences in * and ability to be * ), and distillation (based on differences in * or * of the mixture components)

A

solubility, adsorbed

volatility, boiling point

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11
Q

simple distillation, which is typically used for two * liquids with boiling points that are * and far from each other.

A

miscible, below 150 °C

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12
Q
  • (for isopropyl alcohol) or about * (for ethyl alcohol).
A

82 to 84 °C

78 to 80 °C

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13
Q

where Ptrapped air is the pressure of gas * , Pbar is the *

A

trapped in the eudiometer

barometric pressure

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14
Q

For all cases, the pressure of gas produced in dry conditions can be calculated as

A

𝑃𝑑𝑟𝑦 𝑎𝑖𝑟 = 𝑃𝑡𝑟𝑎𝑝𝑝𝑒𝑑 𝑎𝑖𝑟 − 𝑃𝑤𝑎𝑡𝑒𝑟 𝑣𝑎𝑝𝑜𝑟

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15
Q

Colligative properties are properties of solutions which depend on the * of the * solutes

A

concentration, non-volatile

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16
Q

One of the general properties of acids and bases is their ability to * acids and bases, respectively, from their corresponding salts

A

displace weaker