4.3 Rates Flashcards

(42 cards)

1
Q

How does increasing temperature increase rate of reaction?

A

particles gain more kinetic energy

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2
Q

How does increasing concentration increase rate of reaction?

A

more particles in the same volume

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3
Q

How does reducing particle size increase the rate of reaction?

A

increases surface area
more contact between reactants

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4
Q

How does using a catalyst increase the rate of reaction?

A

reduces activation energy, provides alternative path

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5
Q

How does changing pressure increase rate of reaction?

A

same particles in smaller volume

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6
Q

What is collision theory?

A

particles must collide with required energy (activation energy) for the reaction

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7
Q

What is activation energy?

A

amount of energy particles need to react

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8
Q

What is collision frequency?

A

how often particles collide with each other

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9
Q

What is percentage success?

A

what percentage of collisions have enough energy

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10
Q

What factors affect rate of reaction?

A

pressure
concentration
surface area
catalyst
temperature

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11
Q

What factors affect collision frequency?

A

concentration
pressure
surface area

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12
Q

What factors affect percentage success?

A

temperature
catalyst

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13
Q

Name an experiment to measure the effect of surface area on rate

A

marble chip experiment

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14
Q

Name an experiment to measure the effect of temperature on rate

A

magnesium and acid experiment

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15
Q

Name an experiment to measure the effect of catalyst on rate

A

hydrogen peroxide experiment

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16
Q

Why are catalysts not included in the equation?

A

because they are unchanged in the reaction

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17
Q

Which catalyst is used in the hydrogen peroxide experiment?

A

manganese oxide

18
Q

How is the scientist able to retrieve the catalyst?

A

it is not used up in the reaction

19
Q

What is a catalyst?

A

substance that increases rate of reaction but remains chemically unchanged

20
Q

How do catalysts work?

A

provide an alternative pathway
percentage of collisions with enough energy is higher
more successful collisions

21
Q

Name an experiment that can demonstrate the effect of concentration on rate

A

disappearing cross experiment

22
Q

What is the disappearing cross experiment?

A

react sodium thiosulphate
solution with hydrochloric acid

23
Q

In the disappearing cross experiment, which solid is produced?

24
Q

What is the equation for the disappearing cross experiment?

A

sodium thiosulphate + hydrochloric acid -> sulphur + water + sulphur dioxide

25
In the disappearing cross experiment, what is the independent variable?
concentration of sodium thiosulphate
26
In the disappearing cross experiment, what is the dependent variable?
time taken for cross to disappear
27
In the disappearing cross experiment, what are the control variables?
volume of solution concentration of HCl temperature
28
What does the disappearing cross experiment prove?
rate is proportional to concentration
29
What is the magnesium and acid experiment?
reacting magnesium with hydrochloric acid
30
Why does the cross disappear in the disappearing cross experiment?
sulphur is produced in suspension - makes solution cloudy so cross is not visible under breaker anymore
31
In the magnesium and acid experiment, what is the independent variable?
temperature of HCl
32
In the magnesium and acid experiment, what is the dependent variable?
time take for Mg to disappear
33
In the magnesium and acid experiment, what are the control variables?
mass and surface area of Mg volume and concentration of HCl
34
What is the equation for the magnesium and acid experiment?
magnesium + hydrochloric acid -> magnesium chloride + hydrogen
35
What does the magnesium and acid experiment prove?
temperature is not proportional to rate
36
What is the equation for rate of a reaction?
rate = collision frequency x percentage success
37
What is the hydrogen peroxide experiment?
hydrogen peroxide broken down into water and oxygen
38
What is the equation for the hydrogen peroxide experiment?
hydrogen peroxide -> water + oxygen catalysed by manganese oxide
39
In the hydrogen peroxide experiment what is the independent variable?
catalyst being used
40
In the hydrogen peroxide experiment what is the dependent variable?
volume of oxygen produced
41
What are the control variables in the hydrogen peroxide experiment?
volume and concentration of hydrogen peroxide temperature mass and surface area of catalyst
42
What does the hydrogen peroxide experiment prove about rate?
catalyst increases rate