6.4 - The effect of changing conditions on equilibrium Flashcards
(5 cards)
Summary of conditions changing and the effect of it on the equilibrium and impact on Kc:
Effect of the catalyst on Kc and equilibrium?
Catalysts increase the rate of both the forward and reverse reactions, reducing the time needed to reach equilibrium following a change.
However, catalysts neither alter the equilibrium position nor the value of Kc.
What doesn’t affect the Kc
While shifts in concentration or pressure can move the equilibrium position, altering the quantities present to counteract the change, Kc remains unchanged at a specific temperature.
how does temperature change affect Kc?
- A decrease in the amount of product at equilibrium causes Kcto decrease.
- An increase in the amount of product at equilibrium causes Kcto increase.
This ensures that the value of Kc aligns with the new position of equilibrium.
What happens if the temperature is increased/decreased?
For an exothermic reaction, increasing temperature shifts the equilibrium towards the reactants (left).
For an endothermic reaction, increasing temperature shifts the equilibrium towards the products (right).