6th Flashcards
to predict how smt might react
or if they have reacted we should look at
movement of electrons
what is a resonance arrow used for
shows the interconversion between 2 different representations of the same molecule
if we draw an arrow from somewhere that place should then have
a positive charge
if we draw an arrow to somewhere that place should have a
negative charge
H+ number of electrons
0
this is a proton
electrons can be shared from a lone pair or a
bond
arrow should be drawn through the C that is making the bond
the C would then have a +
species giving the electrons is called a
nucleophile
attracted to positive
species that receive the electrons
electrophile
attracted to the negative
the higher the enthalpy of hydrogenation
the less stable it is
more energy released
energy released when smt is heated up
when double bonds and single bonds alternate
conjugated alkenes
what is a property of conjugated alkenes
they are more stable than expected
they release less energy than expected
different between conjugated and non conjugated alkenes
conjugated: pi orbitals overlap and interact + overlap allowing greater stability
non conjugated: pi orbitals are not close enough to interact + overlap and increase stability
how come they both have pi orbitals??
alkenes : sp2 hybridised meaning one 1 orbital is not hybridised and is free
orbitals
regions of space where electrons are likely to be found
nodes
areas of space where the probability of finding an electron is 0
points of 0 electron density