Acid-Base Titrations Flashcards

(92 cards)

1
Q

pH meter measures the _______ produced in the solution

A

voltage

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2
Q

blue paper turns red at pH?

A

<5

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3
Q

They defined acid-base reactions as processes that involve the transfer of proton (H+) from one substance to another. The one which donates the proton is the acid while the one that accepts the proton is the base.

A

Johannes Brønsted and Thomas Lowry

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4
Q

red paper turns blue at pH?

A

8

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5
Q

These are aqueous systems that tend to resist changes in pH when small amounts of acid (H⁺) or base (OH⁻) are added

A

Buffers

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6
Q

are important because it tells you the pH of the solution at the equivalence point

A

Titration Curves

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7
Q

CH3COOH has a conjugate base pair

A

CH3COO-

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8
Q

If [H3O+] is higher, then it is

A

acidic

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9
Q

Weak acid and a Conjugate base in a sol’n will give you

A

Buffer Solution

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10
Q

For less accurate method, one can use this to measure the pH of a solution

A

litmus papers

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11
Q

For more accurate measurements, a ___________ is used which measures the voltage produced in the solution.

A

pH meter

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12
Q

The one that accepts the proton is the

A

Base

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13
Q

What happens to pH at equivalence point?

A

changes drastically so the curve is somewhat vertical at equivalence point

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14
Q

have two ionizable protons

A

Diprotic acids

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15
Q

Since strong acids and bases completely dissociates in solution, the equilibrium concentrations of H3O+ (for acids) and OH- (for bases) are?

A

equal to their initial concentrations

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16
Q

pH range where the buffer is most effective in resisting pH change

A

Buffer Range

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17
Q

The only difference between conjugate pairs is the transfer of

A

H+

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18
Q

The one which donates the proton is the

A

Acid

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19
Q

One common example of amphiprotic substances

A

water

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20
Q

A solution in which [H3O+] is equal to [OH-] is called

A

Neutral

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21
Q

encompass all acids containing more than one ionizable H

A

polyprotic acids

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22
Q

This property of water where it can act as either a Bronsted-Lowry acid or a Bronsted-Lowry base is called

A

autoionization

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23
Q

He defined acids as substances that, when dissolved in pure water, increase the concentration of H+ ions, and bases are those that increase the concentration of OH− ions.

A

Svante Arrhenius

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24
Q

It completely dissociates in solution

A

strong acids and strong bases

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25
plots the pH of the solution against the volume of titrant added
Titration Curves
26
acids as substances, when dissolved in pure water, increase the concentration of H+ ions, and bases are those that increase the concentration of OH− ions.
Arrhenius Definition
27
They proposed a more general description for acids and bases.
Johannes Brønsted and Thomas Lowry
28
indicates the end point of the titration
Acid-Base Indicators
29
The equilibrium constant of the weak base is therefore called the
base-dissociation constant, Kb
30
A proton donor and its corresponding proton acceptor make up a
conjugate acid-base pair
31
The buffering power at midpoint is
maximal
32
acts in the cytoplasm of all cells
Phosphate buffer system
33
at half equivalence point, you will have
Buffer Solution
34
There are substances that are capable of donating and accepting protons called
Amphiprotic substances
35
This equilibrium constant of weak acid is called the
acid-dissociation constant, Ka
36
higher [OH-] is considered
basic
37
NH3 has a conjugate acid pair
NH4+
38
These are mixtures of weak acids and their conjugate bases
Buffer systems
39
In all acid-base reactions, the products will always be the ________________ of the other
conjugate pair
40
The pH range of your indicator must be near the _____________________
Equivalence Point
41
The higher the value of Ka
the stronger the acid
42
This property of water where it can act as either a
Bronsted-Lowry acid or a Bronsted-Lowry base
43
solutions containing a weak acid and its conjugate base, or a weak base and its conjugate acid
Acid-Base Indicators
44
pH of an acidic solution
< 7.00
45
pH of a neutral solution
= 7.00
46
pH of a basic solution
> 7.00
47
[H+][(M) of an acidic solution
> 1.0 x 10^-7
48
[H+][(M) of a neutral solution
= 1.0 x 10^-7
49
[H+][(M) of a basic solution
< 1.0 x 10^-7
49
[OH-][(M) of an acidic solution
< 1.0 x 10^-7
50
[OH-][(M) of a basic solution
> 1.0 x 10^-7
51
[OH-][(M) of a neutral solution
= 1.0 x 10^-7
52
pH + pOH = pKw= ?
14
53
the equilibrium concentrations of H3O+ (for acids) and OH- (for bases) are equal to their
initial concentrations
54
The higher the value of Ka, the __________ the acid.
stronger
55
where HA is a weak acid and its conjugate base is A-, the equilibrium constant is called the?
acid-dissociation constant, Ka
56
where HB is the conjugate acid of the base, the equilibrium constant expression is called the
base-dissociation constant, Kb
57
the higher the value of Kb, the __________ the base
stronger
58
have two ionizable protons
diprotic acids
59
encompass all acids containing more than one ionizable H
polyprotic acids
60
The stronger the acid, the __________ its pKa
lower
61
the stronger the base, the ___________ its pKa
higher
62
examples of strong acids
Perchloric acid Chloric acid Hydrobromic acid Hydrochloric acid Hydroiodic acid
63
examples of strong bases
Potassium hydroxide Lithium hydroxide Rubidium hydroxide Sodium hydroxide Strontium hydroxide
64
These are aqueous systems that tend to resist changes in pH when small amounts of acid (H⁺) or base (OH⁻) are added
Buffers
65
where the buffer is most effective in resisting pH change
Buffer range - pH range
65
These are mixtures of weak acids and their conjugate bases.
Buffer systems
66
The buffering power at midpoint is
maximal
67
A proton donor and its corresponding proton acceptor make up a
conjugate acid-base pair
68
The only difference between conjugate pairs is the transfer of
H+
68
In all acid-base reactions, the products will always be the ____________________ of the other.
conjugate pair
69
expression that relates pH, pKa, and buffer concentration
Henderson-Hasselbalch Equation
69
these are equal at midpoint
pH and pKa
69
Henderson-Hasselbalch equation also allows us to calculate ________, given pH and the molar ratio of proton donor and acceptor
pKa
70
Henderson-Hasselbalch equation also allows us to calculate ________, given pKa and the molar ratio of proton donor and acceptor
pH
70
Henderson-Hasselbalch equation also allows us to calculate the __________________________, given pH and pKa
molar ratio of proton donor and acceptor
71
__[buffer], ↓ΔpH, ↑ buffer capacity
71
factors affecting buffer capacity
1. concentration of the two buffer components 2. pH
72
↑[buffer], __ΔpH, ↑ buffer capacity
73
↑[buffer], ↓ΔpH, __buffer capacity
74
buffer is most effective (ΔpH) when the acid is ________ since it gives greater capacity to neutralize the added base
higher
75
buffer is most effective (ΔpH) when the acid is higher since it gives ___________________ to neutralize the added base
greater capacity
76
acts in the cytoplasm of all cells, consists of H2PO4⁻ as proton donor and HPO42−as proton acceptor:
phosphate buffer system
76
Blood plasma is buffered in part by the bicarbonate system, consisting of carbonic acid (H2CO3) as proton donor and bicarbonate (HCO3⁻) as proton acceptor
bicarbonate system
76
these are two especially important biological buffers
1. Phosphate buffer system 2. Bicarbonate system
77
proton donor in phosphate buffer system
H2PO4-
78
proton acceptor in phosphate buffer system
HPO4^2-
79
proton donor in bicarbonate system
H2CO3
80
proton acceptor in bicarbonate system
HCO3-
81
Titration curves are important because it tells you the pH of the solution at the?
equivalence point
82
solutions containing a weak acid and its conjugate base, or a weak base and its conjugate acid
acid-base indicators
83
The pH range of your indicator must be near the?
equivalence point