Aldehyde and Ketones Flashcards

(32 cards)

1
Q

aldehydes and ketones are often called __ or __

A
  • formyl
  • methanoyl
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2
Q

aldehydes derive their name form the __ _ __

A

dehydration of alcohols

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3
Q

aldehydes contain the carbonyl group bonded to at least __ __ __

A

one hydrogen atom

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4
Q

ketones contain carbonyl group bonded to __ __ __

A

two carbon atoms

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5
Q

IUPAC system of nomenclature assigns a characteristic suffix __ to aldehydes

A

-al

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6
Q

where should you start counting in aldehyde

A

starting at aldehyde group

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7
Q

when naming the parent chain of an aldehyde attached to a ring, the suffix __ is added to the end of the ring name

A

-carbaldehyde

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8
Q

6 carbon ring cyclohexane with aldehyde

A

cyclohexanecarbaldehyde

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9
Q

IUPAC system of nomenclature assigns a characteristic suffix __ to ketones

A

-one

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10
Q

where should you start counting in ketones

A

closest to the ketone group

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11
Q

aldehydes have a __ __ than ketones

A

higher priority

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12
Q

for dialdehydes the location numbers for both carbonyls are __

A

omitted

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13
Q

for diketones both carbonyl require a __ __

A

location number

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14
Q

in naming, the functional group with carbonyl is given the __ priority

A

Highest

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15
Q

when an aldehyde or ketone is present in a molecule which also contains alkene functional group, the carbonyl is given nomenclature __ by the IUPAC system

A

priority

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16
Q

fragment with carbonyl group

A

alkanoyl (acyl, older)

17
Q

group consisting of a carbonyl group bonded to a hydrogen atom

18
Q

group consisting of a carbonyl group bonded to CH3 fragment

19
Q

monosaccharides containing aldehdyes are called __ and __ for ketones

A
  • aldose
  • ketose
20
Q

breakdown of fats that produce ketones

21
Q

source of ketones from alkyne

A

hydration of alkynes

22
Q

other aldehydes and ketones continuing up to eleven carbon atoms are __ __ while stil higher members are __

A
  • colorless liquid
  • solids
23
Q

lower aldehydes have __ odors

24
Q

other aldehydes and ketones have a __ __

A

pleasant smell

25
solubility of aldehydes and ketones up to 4 carbon atoms
soluble in water
26
solubility of aldehydes and ketones __ by increasing the length of alkyl chain
decreases
27
aldehydes and ketones have __ boiling point than non-polar compounds but have __ boiilng point than corresponding alcohols or carboxylic acids
- higher (than hydrocarbons) - lower
28
due to the presence of carbon-oxygen double bonds in aldehydes and ketones, they are __ in nature
polar
29
Aldehydes and ketones can be prepared by a number of methods
1. Hydration of alkynes 2. Ozonolysis of certain alkenes 3. Oxidation of Alcohols
30
All alkynes react with water in the presence of HgSO4 and H2SO4 catalyst to yield an __
enol
31
reaction method in which addition of ozone molecules or O3 to an alkene compound leads to the formation of ozonide
ozonolysis of alkenes
32
addition of ozone molecules or O3 to an alkene compound leads to the formation of __
ozonide