aldehyde and ketones Flashcards

1
Q

how are aldehydes oxidised into carboxylic acids

A

heating under reflux with potassium dichromate and concentrated sulphuric acid, carbonyl contain permanent dipole making them susceptible to nucleophilic addition reactions

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2
Q

how is aldehyde reduced to primary alcohols and ketone to secondary alcohols

A

using NaBH4 in aqueous solution, these reduction reactions are nucleophilic addition reactions.

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3
Q

hazards of using kcn

A

can be toxic and irritant to the skin

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4
Q

why can nucleophilic addition reaction of KCN with dilute acid produce a mixture of enantiomers

A

they produce entanitomers and as they are 2 optical isomers there is an equal chance of each isomer being formed within the racemic mixture

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