aromatic chemistry Flashcards

1
Q

structure in a benzene ring

A

compounds with benzene are aromatic they have a planar cyclic structure consigns f a ring of carbon atoms each with a single hydrogen atom sticking out into a flat plane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

nature of bonding in a benzene ring

A

delocalised electron system arise due to overlap of one p oribtal from each carbon atom above and below the plane of ring, electrons are shared evenly so all bond length are the same between the bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

why is benzene more stable than theoretical molecules

A

the delocalisation of p electrons means there are alternating double and single bonds that is reflected in the hydrogenation of benzene being less exothermic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

explain why substitution reactions occur in preference to addition reactions

A

because lots of energy is needed to disrupt the delocalised system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

electrophilic substitution of benzene

A

electrophilic attack on benzene rings result in substitution , the benzene ring is a region of high electron density which means it attracts electrophiles

How well did you know this?
1
Not at all
2
3
4
5
Perfectly