alkene Flashcards
(13 cards)
pi bond
.electron density above and below atom
.no rotation
sterioisomerism
.same strutucal but diff arrangement in space
cis/trans
.cis = when same group is on the same side
.trans = when same group is on the oppo side
E/Z
prioity = mass of atom not whole group
if same = add mass of the atoms bonded to it
alkene shape
120 trigonal planer
hydrogenation
alkene + H2 and Ni catalyst –> alkane
alkene test
add bromine water and shake
= colourless
alkene + H2O
conditions = steam and H3PO4
makes alcohol
polymerisation
-[C-C]-n
alkene + halogen mechanism (electrophillic addition)
Br-Br = top is slightly negative /bottom is positive
.arrow from C=C to Br positive
.arrow from Br-Br bond to negative Br
.alkane with a Br and a positive C
.Br- outside
.arrow from lone pair on Br- to C+
.forms dibromo alkene
electrophile
electron pair acceptor
addition of hydrogenhalide to alkene
.halogen on top and negative
.same as other mechanism but hydrogen goes first
how to dispose of polymers
.crack the carbon chains to form many small alkenes and one new alkanes to make organic feedstock
.or burn them but HCl gas is bad