Atomic structure Flashcards
(12 cards)
What are isotopes?
Atoms of the same element that have the same number of protons but different numbers of neutrons.
Definition of relative atomic mass
Average mass of the naturally occurring isotopes of an element relative to carbon-12.
Definition of 1st ionisation energy
The energy required to remove one mole of electrons from one mole of gaseous atoms to form one mole of gaseous positive ions.
Definition of 2nd ionisation energy
Energy required to remove one mole of electrons from one mole of gaseous positive ions to form one mole of dipositive ions.
What is this equation showing?
H(g) —> H+(g) + e-
First ionisation energy
What is this equation showing?
Ti+(g) —> Ti2+(g) + e-
2nd ionisation energy
What happens in ionisation
Positive ions are formed (converted into positive charges)
What is electrospray?
- high voltage needle
- molecule gains a H+
What is electron impact?
- Electron gun
- Knocks off electrons
What happens in acceleration (mass spectroscopy)?
Positively ions are accelerated towards a negatively charged plate
Ion drift (mass spectroscopy)
Ions drift at the same speed as they left the electrical field
What happens in detection (mass spectroscopy)?
When the positive ion hits the detector, they gain an electron and generates current. The greater the the current means the greater the abundance.