Bonding Flashcards

(32 cards)

1
Q

cation

A

positively charged ion

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2
Q

anion

A

negatively charged ion

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3
Q

dative bond

A

a covalent bond where both electrons in the shared pair are donated from the same atom

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4
Q

Covalent bond

A

the electrostatic attraction between nuclei of two non metal atoms and the bonding electrons of their outer shells. no electrons are transferred, they are only shared

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5
Q

shorter bond length means

A

greater bond strength as bonding pair is closer to atoms nucleus

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6
Q

as number of shared electrons increases, bond length

A

decreases

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7
Q

linear bond angle

A

180

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8
Q

trigonal planar bond angle

A

120

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9
Q

tetrahedral bond angle

A

109.5

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10
Q

trigonal bipyramidal bond angle

A

90 and 120

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11
Q

octahedral bond angle

A

90

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12
Q

how many degrees is subtracted when a bond pair is replaced with a lone pair eg: trigonal planar to bent

A

-2

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13
Q

valence shell electron pair repulsion theory

A

All pairs of valence electrons will repel each other to the maximum separation that they can where they experience the minimum amount of repulsion.

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14
Q

pyramidal bond angle

A

107

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15
Q

bent bond angle

A

118 or 104.5

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16
Q

do bond pairs or lone pairs repel more

17
Q

electronegativity

A

Measures the attraction of a bonded atom for the pair of electrons in a covalent bond

18
Q

3 most electronegative elements

A

Fluorine, oxygen and nitrogen

19
Q

dipole

A

an area of slight positive or negative charge

20
Q

what leads to a polar covalent bond

A

electronegativity difference

21
Q

where does an electron lie in a polar covalent bond and what does this cause

A

closer to the more electronegative atom, giving the more electronegative atom a slight negative charge and the less electronegative atom a slight positive charge

22
Q

polar molecule

A

a molecule which can be split into 2 overall dipoles

23
Q

can symmetrical molecules be polar, why

A

no because the dipoles for each end cancel out

24
Q

dipole-dipole interactions

A

both molecules have permanent dipoles which cause them to attract eachother

25
dipole-induced dipole interactions
permanent dipole induces a dipole on another molecule which causes them to attract
26
london forces
instantaneous dipoles form due to electron movement causing momentary attraction
27
what happens to london forces as the size of a molecule increases, why
the strength of london forces increases as there are more electrons to form a stronger instantaneous dipole
28
order of intermolecular forces in increasing strength
london forces -----> dipole-dipole -----> hydrogen bonds
29
where does hydrogen bonding occur
between molecules that have a F, O or N that has a lone pair of electrons and is also covalentally bonded to a H atom
30
what is a hydrogen bond
an extra strong dipole-dipole interaction
31
why is water denser than ice
hydrogen bonds in water holds molecules closer together than the lattice it forms when frozen
32