Bonding Flashcards

1
Q

cation

A

positively charged ion

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2
Q

anion

A

negatively charged ion

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3
Q

dative bond

A

a covalent bond where both electrons in the shared pair are donated from the same atom

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4
Q

Covalent bond

A

the electrostatic attraction between nuclei of two non metal atoms and the bonding electrons of their outer shells. no electrons are transferred, they are only shared

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5
Q

shorter bond length means

A

greater bond strength as bonding pair is closer to atoms nucleus

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6
Q

as number of shared electrons increases, bond length

A

decreases

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7
Q

linear bond angle

A

180

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8
Q

trigonal planar bond angle

A

120

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9
Q

tetrahedral bond angle

A

109.5

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10
Q

trigonal bipyramidal bond angle

A

90 and 120

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11
Q

octahedral bond angle

A

90

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12
Q

how many degrees is subtracted when a bond pair is replaced with a lone pair eg: trigonal planar to bent

A

-2

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13
Q

valence shell electron pair repulsion theory

A

All pairs of valence electrons will repel each other to the maximum separation that they can where they experience the minimum amount of repulsion.

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14
Q

pyramidal bond angle

A

107

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15
Q

bent bond angle

A

118 or 104.5

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16
Q

do bond pairs or lone pairs repel more

A

lone pairs

17
Q

electronegativity

A

Measures the attraction of a bonded atom for the pair of electrons in a covalent bond

18
Q

3 most electronegative elements

A

Fluorine, oxygen and nitrogen

19
Q

dipole

A

an area of slight positive or negative charge

20
Q

what leads to a polar covalent bond

A

electronegativity difference

21
Q

where does an electron lie in a polar covalent bond and what does this cause

A

closer to the more electronegative atom, giving the more electronegative atom a slight negative charge and the less electronegative atom a slight positive charge

22
Q

polar molecule

A

a molecule which can be split into 2 overall dipoles

23
Q

can symmetrical molecules be polar, why

A

no because the dipoles for each end cancel out

24
Q

dipole-dipole interactions

A

both molecules have permanent dipoles which cause them to attract eachother

25
Q

dipole-induced dipole interactions

A

permanent dipole induces a dipole on another molecule which causes them to attract

26
Q

london forces

A

instantaneous dipoles form due to electron movement causing momentary attraction

27
Q

what happens to london forces as the size of a molecule increases, why

A

the strength of london forces increases as there are more electrons to form a stronger instantaneous dipole

28
Q

order of intermolecular forces in increasing strength

A

london forces —–> dipole-dipole —–> hydrogen bonds

29
Q

where does hydrogen bonding occur

A

between molecules that have a F, O or N that has a lone pair of electrons and is also covalentally bonded to a H atom

30
Q

what is a hydrogen bond

A

an extra strong dipole-dipole interaction

31
Q

why is water denser than ice

A

hydrogen bonds in water holds molecules closer together than the lattice it forms when frozen

32
Q
A