Group 2 and 7 Flashcards

1
Q

what factors affect the ionisation energies of the alkali and alkaline earth metals?

A

size of the ion and charge of the ion

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2
Q

size of the ion ….. down group 2, why

A

increases, due to more shielding and less nuclear attraction

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3
Q

group 2 metal + water

A

metal hydroxide + hydrogen

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4
Q

group 2 metal + oxygen

A

metal oxide

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5
Q

group 2 metal + chlorine

A

metal chloride

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6
Q

reactivity of group 2 metal oxides …… down the group

A

increases

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7
Q

group 2 metal oxide + water

A

metal hydroxide

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8
Q

group 2 metal oxide + acid

A

salt + water

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9
Q

group 2 metal hydroxide + acid

A

salt + water

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10
Q

solubility of group 2 metal hydroxides ….. down the group

A

increases

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11
Q

magnesium hydroxide uses

A

as a laxative or for indigestion

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12
Q

solubility of group 2 metal sulphates ……. down the group

A

decreases

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13
Q

barium sulphate uses

A

barium meal to cause contrast in x rays

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14
Q

Thermal stability

A

a measure of resistance to thermal decomposition.

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15
Q

Thermal decomposition

A

when a substance breaks down when heated.

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16
Q

Polarizing power of a cation

A

its ability to pull the electrons from the anion into the space between the ions

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17
Q

What 2 things affect polarising power?

A

size of the ion, charge density

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18
Q

how does a cation polarise a carbonate

A

distorts the carbonate ion. This weakens the C-O bond

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19
Q

thermally stability of group 2 metal carbonates …….. down the group, why?

A

increases due to decreased charge density so decreased polarisation of the carbonate ion

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20
Q

thermal decomposition of a group 2 metal carbonate forms

A

metal oxide + carbon dioxide

21
Q

fluorine properties

A

pale yellow gas at room temperature

22
Q

chlorine properties

A

pale green gas at room temperature

23
Q

bromine properties

A

brown liquid at room temperature

24
Q

iodine properties

A

black/grey solid at room temperature

25
oxidising power of halogens ....... down the group, why
decreases, due to less nuclear attraction from shielding so harder to attract electrons to accept
26
reducing power of halide ions ...... down the group, why
increases, due to less nuclear attraction from shielding so requires less energy to donate an electron
27
Disproportionation
the same atom is simultaneously reduced and oxidised
28
Cl2 + H2O
HCl + HOCl
29
Cl2 + NaOH (cold and dilute)
NaCl + NaClO + H2O
30
3Cl2 + 6NaOH (hot and concentrated)
5NaCl + NaClO3 + 3H2O
31
Li+ flame test
crimson
32
Na+ flame test
Yellow
33
K+ flame test
lilac
34
Ca2+ flame test
red
35
Ba2+ flame test
green
36
Al3+ with NaOH
white ppt, dissolves in excess
37
Ca2+ with NaOH
white ppt, does not dissolve in excess
38
Mg2+ with NaOH
white ppt, does not dissolve in excess
39
Cu2+ with NaOH
pale blue ppt, does not dissolve in excess
40
Fe2+ with NaOH
pale green ppt which turns brown when left, does not dissolve in excess
41
Fe3+ with NaOH
brown ppt, does not dissolve in excess
42
what is used to clean nichrome wire for flame test
concentrated hydrochloric acid
43
where should you hold the wire in a flame test
in the edge of the flame
44
Cl-, Br- and I- colour ppt in silver nitrate
Cl- = white Br- = cream I-= yellow
45
positive carbonate test will
turn limewater cloudy
46
positive nitrate test will
turn red litmus paper blue with aluminium powder and sodium hydroxide
47
sulphate test with dilute hydrochloric acid and barium sulphate will form
white precipitate
48
why are flame test colours formed
heat energy excites electrons to a new energy level, a photon is released when they fall back down. This photon directly relates to the wavelength of visible light.
49