Bonding Flashcards

(52 cards)

1
Q

*Orbital

A

A region around the nucleus that can hold up to two electrons, with opposite spins

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2
Q

*ionic bonding

A

The electrostatic attraction between oppositely charged ions.

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3
Q
  • covalent bonding
A

Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms

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4
Q

*polar molecule

A

has polar bonds with dipoles that do not cancel due to their direction

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5
Q

*electronegativity

A

the ability of an atom to attract the bonding electrons in a covalent bond

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6
Q

Dipole

A

: partial charged atoms in a covalent bond due to different electronegativity

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7
Q

allotropes

A

different forms of the same element in the same state, e.g graphite and diamond

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8
Q

dative covalent bond

A

When both electrons come from one atom in a covalent bond.

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9
Q

when and why can ionic compounds conduct electricity

A

Ionic compounds don’t conduct as solid due to no mobile ions, they can conduct when molten/ in solution as ions are mobile.

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10
Q

can covalent compounds conduct electricity? why?

A

Covalent compounds can’t conduct as solids or liquids/solutions as they have no ions or mobile electrons.

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11
Q

can metals conduct electricity

A

Metals can conduct when solid or molten as they have delocalised electrons.

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12
Q

When explaining shapes of molecules or bond angles state:

A

o Number of bond pairs and lone pairs of electrons
o Electron pairs repel so spread out
o Lone pairs repel more than bonded pairs

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13
Q

what is an induced dipole- dipole

A

caused by movement of electrons causing a temporary dipole which induces a dipole in a neighbouring molecule. The more electrons a molecule has the larger the force, e.g. I2 has lots of electrons so induced dipole forces are strong enough that it’s a solid.

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14
Q

what is a permanent dipole

A

a difference in electronegativity causes a permanent dipole so molecules are attracted to each other.

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15
Q

what is hydrogen bonding

A

occurs between molecules that have N, O or F with a lone pair and H attached. Strong compared to other IM bonds

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16
Q

what are the rules of orbitals

A

the two electrons have opposite spins

the orbitals in he same sub shell fill up singly before pairing up

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17
Q

shape of s orbital

A

spherical

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18
Q

shape of p orbital

A

3d - dumbell shape

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19
Q

how many orbitals and electrons are in the s sub-shell

A

1 orbital

2 electrons

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20
Q

how many orbitals and electrons are in the p sub-shell

A

3 orbitals

6 electrons

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21
Q

how many orbitals and electrons are in the d sub-shell

A

5 orbitals

10 electrons

22
Q

how many orbitals and electrons are in the f sub-shell

A

7 orbitals

14 electrons

23
Q

what sub-shells are in the first shell (and electrons)

A

1s - 2 electrons

24
Q

what sub-shells are in the second shell (and electrons)

A

2s 2p - 8 electrons

25
what sub-shells are in the third shell (and electrons)
3s 3p 3d - 18 electrons
26
what sub-shells are in the fourth shell (and electrons)
4s 4p 4d 4f - 32 electrons
27
what is a cation
metal ion | positive
28
what is an anion
non-metal ion | negative
29
what is a giant ionic lattice
giant regular structure with electrostatic attraction in all directions
30
properties of ionic compounds
- high melting and boiling point (strong bonds) - electrical conductor in liquids and solution - soluble in water (ions are attracted to the polar water molecules)
31
what is average bond enthalpy
measures the energy required to break a covalent bond
32
2 bonded pairs, 180 degrees
linear shape
33
linear shape
2 bonded pairs, 180 degrees
34
3 bonded pairs, 120 degrees
trigonal planar
35
trigonal planar
3 bonded pairs, 120 degrees
36
tetrahedral
4 bonded pairs, 109.5 degrees
37
4 bonded pairs, 109.5 degrees
tetrahedral
38
3 bonded pairs, 107 degrees
trigonal pyramidal
39
trigonal pyramidal
3 bonded pairs, 107 degrees
40
bent/ non-linear
2 bonded pairs, 2 lone pairs, 104.5 degrees
41
2 bonded pairs, 2 lone pairs, 104.5 degrees
bent/ non-linear
42
trigonal bi pyramidal
5 bonded pairs, 120 degrees, 90 degrees
43
5 bonded pairs, 120 degrees, 90 degrees
trigonal bi pyramidal
44
octrahedral
6 bonded pairs, 90 degrees
45
6 bonded pairs , 90 degrees
octrahedral
46
what is a polar bond
a bond where the electron are unevenly distributed due to a difference in electronegativity
47
why is ice less dense than water
long hydrogen bonds break making water denser
48
why does water have a relatively high melting point
stronger inter molecular forces (hydrogen)
49
when does hydrogen bonding happen
hydrogen with fluorine, nitrogen, oxygen
50
why do simple covalent compounds have low melting points
inter molecular forces are weaker than intramolecular forces
51
why are polar molecules soluble in water (s.c.)
dissolves polar molecules or forms hydrogen bonds
52
what do simple covalent not conduct electricity
overall uncharged