C2 structure,bonding and the properties of matter Flashcards

1
Q

Ionic bonding

A

Metals and non metals
Partials are oppositely charged ions
Structure- large crystals made from ions attracted to each other by electrostatic attraction
Room temp- solids
Melting point- high
Conductor of electricity- not when solid, yes when molten

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2
Q

Covalent bonding

A

Compounds of non metals and in most non metallic elements
Atoms that share pairs of electrons
Structure- molecules made from atoms bonded by covalent bonds
Room temp- liquid and gases
Melting point- low
Conductor of electricity- no or very little
Very strong

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3
Q

Metallic bonding

A

Metallic elements and alloys
Atoms that share delecoalised electrons
Structure- lumps or sheets of metal made from atoms packed together so that the delocalised electrons move through the fixed position
Room temp- solids (expect Mercury liquid)
Melting point- high
Sharing delocalised electrons makes strong bonds
Conductor of electricity- yes, good conductor

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4
Q

When metals and non metals transfer electrons

A
Atoms become charged. Make ions.
Metal is positively charged
Non metal is negatively charged 
Ionic bonding
Positive and negative attracted by electrostatic attraction
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5
Q

Why do atoms bond

A

To make stable electronic structures
It is easier for metals to lose electrons and become positive ions
And easier for non metals to gain electrons to become negative ions

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6
Q

Giant structures

A

An ionic compound is a giant structure of ions in a lattice

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7
Q

Ball and stick diagram pros

A

The structure in 3D
The charges on the ions
The arrangement of ions in 3D
The type of ions in all directions

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8
Q

Ball and stick cons

A

Ions are actually closer together

Gives false image of bond direction when it is only electrostatic attraction

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9
Q

Ball and stick best represents

A

The number and type of ions in 3D

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10
Q

Close packed pros

A
The structure in 3D
The charges on the ions
The arrangement of ions
In 2D (look at the front face of the diagram)
The closeness of ions
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11
Q

Close packed cons

A

Difficult to see arrangement of ions in 3D

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12
Q

Close packed best represents

A

The way that ions are packed close together

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13
Q

States of matter

A
Solid} sublimation} gas
Gas} condensation} liquid 
Liquid} boiling} gas
Liquid} freezing} solid
Solid} melting} liquid
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14
Q

In melting and boiling

A

Forces between particles decrease
Distance between particles increases
Arrangement becomes more random
Particles move more so need more energy from surroundings

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15
Q

In freezing and condensing

A

The strength of the particles remains the same
Distance between particles decreases
Arrangement becomes less random
Particles move less so less energy required from surroundings

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16
Q

Limitations of simple model

A

There are no forces represented between spheres
All particles represented as spheres
The spheres are represented as solid and inelastic

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17
Q

Small molecule

A

2 or 3 atoms joined together with no charge
Relatively low melting points and boiling points
Weak intermolecular forces
Can’t conduct electricity as have no charge

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18
Q

Polymers

A

Very large molecules
Atoms are linked to other atoms by strong covalent bonds
Form long chains
Intermolecular forces between polymer molecules are weaker
Allow chains to slide over each other but not pulled apart

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19
Q

Intramolecular bonds

A

The atoms of the monomers along the chains in a polymer are held together by strong covalent bonds. These are bonds within the polymer molecules

20
Q

Intermolecular

A

The chains of the polymer are held together by weak forces of attraction. These forces between polymer molecules

21
Q

Weak intermolecular forces of attraction

A

Stretches easily

Lower melting point

22
Q

Strong cross linkes- chemical bonds between the chains

A

Rigid

Higher melting points

23
Q

Making polymers

A

By addition

By condensation

24
Q

Addition polymers

A

Long chains of units made from one molecule that has at least 1 double bond between carbon atoms
πŸ”΄βž–πŸ”΄βž–πŸ”΄βž–πŸ”΄βž–πŸ”΄βž–πŸ”΄

25
Condensation polymers
Made of units using at least 2 different molecules Losing a water molecule in the process πŸ”΄βž–πŸ”Άβž–πŸ”΄βž–πŸ”Άβž–πŸ”΄βž–πŸ”Ά
26
Giant covalent structures
All atoms are linked to each other by strong covalent bonds | Eg. Diamond,silicon dioxide
27
Diamond properties
``` Lustrous Transparent Colourless Very hard Very high melting point Insoluble in water Doesn't conduct electricity ```
28
Silicon dioxide
``` White crystalline solid Very hard Very high melting point Insoluble in water Does not conduct electricity ```
29
Forms of carbon
Diamond Graphite Structures are very different
30
Structure of diamonds
Each carbon atom forms 4 bonds Forms tetrahedron shape The 4 covalent bonds makes it very hard to break Carbon atoms share electrons
31
Graphite
Made from carbon Carbon atoms only make 3 covalent bonds Make hexagonal rings which form layers Cut across layers but not through layers No covalent bonds between layers High melting point Weak forces hold layers together Sea of delocalised electrons conducts electricity Delocalised electrons move easily along layers
32
Uses of graphite
Electrodes - conducts electricity Lubricant- layers slide over each other High temp lubricant- high melting point
33
Graphene
Single layer of graphite One atom thick Hexagonal rings of carbon atoms connected with strong covalent bonds
34
Fullerenes
Carbon rings can form hollow 3D shapes
35
Buckminsterfullerene | Bucky ball
Rings of 5&6 carbon atoms C60 Spherical shape Used in medicine
36
Uses of fullerenes
``` Drug delivery into the body Lubricants Catalysts Act as hollow cages to trap other molecules Make nanotubes ```
37
Nanotube properties
High tensile strength High electrical conductors High thermal conductivity
38
Nanotube uses
Semi conductors in electrical circuits As catalysts Reinforcing materials eg. Tennis rackets
39
Properties of graphene
``` 2D compound Thermally stable Monolayer Electrical conductor through 'ballistic transport' Strongest material ever Elastic Absorb white light ```
40
Nanoparticals
Between 1&100 nm in size Most are made from metals,metal oxides and silicates Each nanoparticle contains only a few hundred atoms
41
When materials are present in nano particles it changes properties
Silver- stops bacteria growing (in clothes/deodorants) Titanium dioxide- protects from ultraviolet light (in sun cream) bigger particles do the same but leave white coating on skin Used to deliver drugs to the right cells
42
Nanoparticle safety
Avoid breathing in as can be hazardous | Could damage organs and tissue
43
Changing surface area to volume ratio | Nanoparticles
When a material becomes a nanoparticle its properties change Gold- displays different colours Titanium dioxide- becomes invisible Silver- destroys bacteria Other materials become more reactive as sa to v ratio increases making them better catalysts
44
Radius of atom
1 x 10-12 m
45
Radius of nucleus
1 x10-15 m