C6 Flashcards
(32 cards)
what is electrolysis
the splitting up of a substance using electricity
why does electrolysis need to be carried out as a molten or dissolved solution
as when it’s molten or dissolved the particles are allowed to move so electricity can flow
what charge is the anode
positive
what charge is the cathode
negative
what an electrolyte
the substance being broken own by electrolysis
which electrode do the negative charged ions go to
the anode (positive node)
which electrode does the positively charged ion go to
the cathode (negatively charged node)
what’s a positive ion called
cations
what’s a negative ion called
anions
what is oxidation
loss of electrons
gain of oxygen
what is reduction
gain of electrons
loss of oxygen
where does reduction happen
at the cathode
where does oxidation happen
at the anode
give the half equation for Mg 2+
Mg2+ + 2e- —-> Mg
what is always produced if an aqueous solution is electrolysed
H+
OH-
the electrolysed electrolyte
give the equation for water undergoing electrolysis
H20 = H+ + OH-
= the symbol for a reversible reaction
what are the 2 rules for aqueous electrolysis
rule 1: the least reactive positive cation (positive ion) will be DISCHARGED at the cathode.
rule 2: if a halide is present as one of the negative anions (negative ion) then that would be DISCHARGED at the anode as a gas. If no halide is present then the OH- will be oxidised and would be DISCHARGED at the anode as 02 gas.
what happens to the H+ and OH- ions at the end of the electrolysis
they react together to form water (pani [pronounce p-ah-knee])
name the reactivity series in order with carbon and hydrogen
potassium
sodium
calcium
magnesium
aluminium
carbon
zinc
iron
tin
lead
hydrogen
copper
silver
gold
platinum
name the formula for a nitrate ion
NO3 -
name the equation for a hydroxide ion
OH 1-
name the equation for a sulphate ion
SO4 2-
name the formula for a hydrogen ion
H 1+
name the equation for a carbonate ion
CO3 2-