Carbohydrates Flashcards

(59 cards)

1
Q

3 functions of carbohydrates

A

Source of energy
Structure
Receptors/information molecules

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2
Q

4 monosaccharides

A

Glucose
Galactose
Fructose
Ribose

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3
Q

How many monomers are in a oligosaccharide?

A

3-9

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4
Q

How many monomers are in a polysaccharide?

A

> 9

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5
Q

4 classes of carbohydrates

A

Momosaccharides
Disaccharides
Oligosaccharides
Polysaccharides

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6
Q

Can carbonhydrates have multiple chiral carbons?

A

Yes

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7
Q

Can carbs both have branched and linear structures?

A

Yes (unlike protein which is only linear)

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8
Q

Are polysaccharides identical?

A

No, they are only similar but always unique

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9
Q

How can carbohydrates be linked to proteins and lipids?

A

Covalently

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10
Q

What are the functional groups that carbohydrates can have?

A

Aldehydes
Ketones

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11
Q

What functional groups do all carbohydrates always have?

A

Carbonyl

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12
Q

On which side is the OH (hydroxyl) group in a D-carbohydrate?

A

The right

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13
Q

On which side is the OH (hydroxyl) group in a L-carbohydrate?

A

The left

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14
Q

What is D-ribose important for?

A

DNA

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15
Q

What are stereoisomers?

A

Nonsuperimposable mirror images

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16
Q

What are D and L isomers of sugars?

A

Enantiomers

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17
Q

What are enantiomers?

A

Stereoisomers that are reflections of eachother, mirror images

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18
Q

What are epimers?

A

Stereoisomers that differ at only one chiral center
They are not mirror images

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19
Q

Are epimers enantiomers?

A

No, as they are not mirror images

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20
Q

Which structure do most carbohydrates have in our body?

A

Cyclic

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21
Q

What are hemiacetals and hemiketals?

A

Derivatives formed by a reaction between alcohol and aldehyde for ketones which also forms the ring structure in a carbohydrate

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22
Q

What are the products od the second alcohol molecule addition in carbohydrates?

A

Acetal or ketal
Forms a glycosidic bond

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23
Q

Difference between pyranoses and furanoses?

A

One is hexagon the other is a pentagon (they have the same number of carbons overall)

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24
Q

Does glucose travel freely in the blood?

25
What are reducing sugers?
Sugars that have free aldehyde groups that can reduce things
26
Are all sugars reducing sugars?
No
27
Can the bond in sucrose easily be cleaved?
Yes
28
Can the bond in lactose easily be cleaved in the body?
In babies yes but that often goes away in humans
29
2 main types of polysaccharides?
Homopolysaccharides Heteropolysaccharides
30
Can polysaccharides be both linear and branched?
Yes
31
What is the monomer of glycogen?
Glucose
32
How many monomers og glucose in glycogen?
We don't know, depends on number of glucose available and so on
33
How often is glycogen branched?
Every 8-12th branch
34
What bonds create glycogen?
Alpha1->4 (linear) Alpha1->6 (branch)
35
2 components of starch
Amylose Amylopectin
36
Is amylose linear or branched?
Linear
37
Is amylopectin linear or branched?
Branched
38
Is starch a big molecule?
Yes
39
What bonds create starch?
Alpha1->4 (linear, amylose) Alpha1->6 (branch, amylopectin)
40
What bonds create cellulose?
Beta1->4
41
Why does cellulose favour the straight chains structure?
Because the angles are most stable at 180*
42
Why does starch and glycogen favour the bent structure?
Because the angles are most stable at 60*
43
Are glucagon and starch soluble?
No they are insoluble
44
Are all polysaccharides insoluble?
no
45
Can we digest beta1->4 bonds?
No
46
How many reducing and non-reducing ends when 2 monomer sugars bind together?
2 non-reducing 0 reducing
47
What is a glycoprotein?
A protein with small oligosaccharides attached One or more carbohydrate groups covalently attached
48
Where does the glycosylation happen?
In the golgi
49
Function of carbohydrates on glycoproteins
Assist protein folding Enhance protein solubility Stabilise against denaturation Protect from proteolytic degradation Target protein specific sub cellular location Recognition signal for carbohydrate-binding proteins (lectins)
50
N-linked glycoproteins are when the carbohydrate binds to what
Aperigine
51
O-linked glycoproteins are when the carbohydrate binds to what
Serine or theorinine
52
Are N-linked carbohydrates branched or linear
Branched
53
Are O-linked carbohydrates branched or linear
Linear in general but can be branched
54
Which carbohydrate is attached to A antigen blood type?
N-aceltylgalactosamine
55
Which carbohydrate is attached to B antigen blood type?
Galactose
56
Which carbohydrate is attached to AB antigen blood type?
N-aceltylgalactosamine and galactose
57
Which carbohydrate is attached to O antigen blood type?
None
58
Which integral membrane proteins are receptors for extracellular proteoglycans?
Integrins
59
Does amylase form helices on its own?
No