carbohydrates Flashcards
(69 cards)
what are carbohydrates?
carbohydrates are organic compounds made up of carbon, hydrogen and oxygen atoms
there are usually twice as many hydrogen atoms as oxygen atoms, in the ratio of 2:1
general formula of carbohydrates
Cₓ(H₂O)ᵧ
all carbohydrates contain several
-OH groups, one attached to every carbon in the skeleton except for the carbonyl group (C=O)
different classes of carbohydrates + their corresponding no. of sugar units
monosaccharides (reducing) - 1
disaccharide - 2
oligosaccharides - 3-10
polysaccharides - >10-1000s
which classes of carbohydrates are considered sugars?
monosaccharides and disaccharides
general formula of monosaccharides
(CH₂O)ₙ , where 3 ≤ n ≤9
different classifications of monosaccharides + their corresponding no. of carbon atoms
(the stuff on the right side dont need memorise)
triose (3C) - e.g. glyceraldehyde
tetrose (4C) - rare
pentose (5C) - e.g. ribose, deoxyribose
hexose (6C) - e.g. glucose, fructose, galactose
heptose (7C)
molecular formula of hexoses (6C sugars)
C₆H₁₂O₆
What functional group does the 1st carbon (¹C) of glucose contain?
an aldehyde group (-CHO)
What functional group is found on carbons ²C to ⁵C of glucose?
Hydroxyl groups (–OH)
In what forms can glucose molecules exist?
Open chain form and stable ring structure
What structure do glucose molecules easily form?
A stable ring structure (like most hexoses and pentoses)
how is the stable ring structure formed?
¹C (with the aldehyde group) reacts favourably with the oxygen atom on ⁵C to form a 6-sided ring structure called a pyranose ring.
what are the two possible ring forms (isomers) of glucose
α-glucose and β-glucose
how to differentiate between α-glucose and β-glucose?
look at the OH group of C1. OH group of alpha is below, OH group of beta is above
ABBA: Alpha below Beta above
common hexose sugars
glucose, galactose, fructose
general formula of disaccharides
C₁₂H₂₂O₁₁
common disaccharides
maltose, lactose, sucrose
a disaccharide consists of
two monosaccharides joined by a glycosidic bond.
formation of a glycosidic bond
A glycosidic bond is formed by a polymerisation reaction called condensation reaction between two monosaccharide units (usually hexoses) combining with the elimination of a molecule of water.
what is a α(1->4) glycosidic bond
a glycosidic bond formed between carbon 1 of one monosaccharide and carbon 4 of the other
describe the breakage of a glycosidic bond
The addition of water, under suitable conditions, is necessary if the disaccharide is to be split into its constituent monosaccharides; this process is known as hydrolysis
the location (animal/plant) of maltose, lactose and sucrose:
maltose: animals and plants
lactose: animals
sucrose: plants
monosaccharide constituents of maltose, lactose and sucrose
maltose: 2 glucose molecules
lactose: glucose and galactose
sucrose: glucose and fructose