Carbohydrates Flashcards

(54 cards)

1
Q

What are carbohydrates made up of

A

C, H, O

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2
Q

What is the general formula for Carbohydrates

A

Cn (H2O)n : N=(3-9)

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3
Q

What are 4 common dietary carbohydrates

A

Starch, Sucrose, Dietary fiber, and Lactose

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4
Q

What is the nutritional reservoir of CH in plants

A

Starch

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5
Q

Starch is a polysaccharide of

A

Glucose

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6
Q

What is amylose

A

unbranched form of starch

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7
Q

What is amylopectin

A

The branched form of starch

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8
Q

natural sweetener and found in fruits and vegetables

A

Sucrose

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9
Q

Sucrose is a disaccharide of ___ and ____

A

glucose and fructose

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10
Q

What is the origin of dietary fiber

A

plants

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11
Q

A major dietary carbohydrate of animal origin

A

Lactose

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12
Q

Lactose is a disaccharide of ____ and _____

A

glucose and galactose

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13
Q

What is the simplest form of carbohydrates

A

Monosaccharides

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14
Q

What are some examples of monosaccharides

A

Glucose, fructose, galactose, ribose

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15
Q

What are two monosaccharides

A

Disaccharides

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16
Q

Maltose, lactose, and sucrose are all

A

disaccharides

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17
Q

Glycolipids and glycoproteins are

A

oligosaccharides

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18
Q

what are oligosaccharides

A

3-10 monosaccharides

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19
Q

What are polysaccharides

A

> 10 monosaccharides

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20
Q

Glycogen, starch, and cellulose are all

A

polysaccharides

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21
Q

what are epimers

A

diastereomers that differ in configuration of only one stereogenic (chiral) center

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22
Q

D-glucose and D-Galactose are examples of

23
Q

What three components will help to identify a monosaccharide

A

Carbon number
Functional group
Stereoisomer form

24
Q

What are the smallest monosaccharides

A

3 carbon atoms (triose)
dihydroxyacetone
D and L- glceraldehyde

25
The D and L nomenclature of a monosaccharide is determined by
position of the OH group farthest from carbonyl carbon
26
Most sugars are in _____ series in humans
D
27
Constitutional isomeers
differ in the order of attachment of atoms
28
Enantiomers
Nonsuperimposable mirror images
29
What are two forms of diastereoisomers
Epimers | Anomers
30
What are anomers
differ at new asymmetric carbon upon ring closure | ex. alpha-D-glucose and beta-D-glucose
31
What are epimers
differ at one of several asymmetric carbons | ex. D-Glucose and D-mannose (or D-galactose)
32
Diastereoisomers
isomers that are not mirror images
33
How is a pyranose formed
mutarotation of D-Glucose leads to ring closure
34
How is a furanose formed
mutarotation of D-Fructose leads to ring closure
35
What is the the preferred form alpha-D-Glucopyranose or beta-D-Glucopyranose
Beta-D-glucopyranose
36
What is the difference between an alpha anemia and a beta anomer
The alpha anomer is on the opposite side of the ring as the Ch2OH The beta anomer is on the same side of the ring from the CH2OH
37
In solution monosaccarides mostly exist as
ring structure
38
Does fructose form both pyranose and furanose rings
yes (pyranose from predominates in fructose that is free in solution, and the furanose form predominates in many fructose derivatives)
39
Deoxyaldose
is a chemically modified monosaccharide derivative | it is a major component of DNA
40
Acetylated amino sugars
chemically modified monosaccharide derivative | They are components of glycoproteins and glycolipids (cell signaling, cell adhesion, immune response)
41
Acidic sugars
Chemically modified monosaccharide derivatives glycosaminoglycans and proteoglycans. present in cell membrane and in the extracellular matrix
42
Sugar esters
Chemically modified monosaccharide derivative | constituted the gangliosides in oligodendrocyte of the nervous system
43
Sugar alcohols (e.g. mannitol, sorbitol, xylitol)
Chemically modified monosaccharide derivatives food additives, gains importance in uncontrolled diabetes leading to cataracts and peripheral neuropathy used in synthesis of lipids
44
sucrose shows what kind of linkage
1-2-glycosidic linkage
45
Lactose demonstrates what kind of linkage
1-4 glycosidic linkage
46
Maltose demonstrates what kind of linkage
1-4 glycosidic linkage
47
starch amylose is a polysaccharide of glucose residues linked with
alpha 1,4-glycosidic bonds
48
Amylopecin is amylose with the addition of
alpha 1,6 glycosidic branch points
49
Cellulose unbranched polymer of glucose residues joined by
Beta-1,4 linkages
50
Starch and glycogen use what kind of linkage
alpha 1,4-glycosidic linkages, these are bent and better for storage
51
O-linkage uses the oxygen on
Serine
52
N-linked glycosidic bonds uses the N on the
Asn
53
The first sugar added to an o-linked glycosidic bond is always
xylose
54
Types of Glycoaminoglycans
Chondroitin sulphate Dermatan sulphate Heparan sulphate Keratan sulfate