CARBOHYDRATES SEMIS Flashcards

(52 cards)

1
Q

A polyhydroxy aldehyde, a polyhydroxy ketone, or a compound that yields polyhydroxy aldehydes or polyhydroxy ketones upon hydrolysis.

A

CARBOHYDRATES

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2
Q

Also known as simple sugars
Highly soluble in water
Less soluble in ethanol
Insoluble in ether

A

MONOSACCHARIDES

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3
Q

Monosaccharides may also be classified into:

A

Tetroses
Pentoses
Hexoses

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4
Q

Formed by two molecules monosaccharides

A

Disaccharides

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5
Q

Are abundant in germinating barley

A

Maltose

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6
Q

Also known as cane sugar or beet sugar

A

Sucrose

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7
Q

This does not taste very sweet and is not fermented by yeast

A

Lactose

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8
Q

Found in nature function either as structural units or for storage such as starch, dextrin, glycogen, insulin

A

Polysaccharides

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9
Q

Give the 4 Polysaccharides for storage

A

Starch
Dextrin
Glycogen
Insulin

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10
Q

Give the 3 general tests for carbohydrates

A

Molisch test
Bial’s orcinol test
Seliwanoff’s test

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11
Q

The general test for carbohydrates

A

Molisch test

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12
Q

In Molisch test the sugars are with a ____

A

A-naphthol

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13
Q

The concentrated H2SO4 will dehydrate the sugar allowing it to react with the alcohol forming a _____

A

Furfural or hydroxymethyl-furfural

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14
Q

When the Molisch test result is colorless, the result is?

A

Negative

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15
Q

When the Molisch test result has a purple/violet ring, the result is?

A

Positive

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16
Q

Used to determine the presence of pentoses and nucleotides and nucleotides that contain pentose sugars

A

Bial’s Orcinol Test

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17
Q

When pentoses are treated with orcinol, furfurals are formed and they will yield a _____ compound in the presence of ferric ion

A

Blue-green compound

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18
Q

Hydroxymethyl furfural is formed from hexoses to give ________ condensation products.

A

Yellow-brown

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19
Q

In Bial’s Orcinol Test what color indicates pentoses

A

Blue-green color

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20
Q

In Bial’s Orcinol Test what color indicates hexoses (negative)

A

Yellow-brown color

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21
Q

This test is used to differentiate keohexoses from aldohexoses

A

Seliwanoff’s test

22
Q

This react faster with the solution containing hydrochloric acid and resorcinol

23
Q

The dehydrated positive ketohexoses form a ______

A

Bright cherry red condensation product

24
Q

Aldohexose yields a ______ that is a negative result

A

Pale pink color

25
Any sugar that, in a solution, has an aldehyde or a ketone group
Reducing sugar
26
Name the 8 reducing sugars
Glucose Galactose Fructose Ribose Glyceraldehyde Xylose Cellobiose Lactose
27
Give the 3 test based on reducing property of sugars
Benedict’s test Barfoed test Tollen’s test
28
It is a very sensitive test done in mildly alkaline conditions
Benedict’s test
29
Benedict’s reagent are composed of;
CuSO4 Na2CO3 Sodium citrate
30
When the Benedict’s reagent changes color the result is?
Positive
31
Used to test the presence of glucose in urine
Benedict’s test
32
Benedicts solution and simple carbohydrates are heated, the solution changes to what color?
Orange red/brick red
33
What is the color of the Benedict’s solution when there are traces of reducing sugar?
Green/yellow
34
What is the color of the Benedict’s solution when there are moderate amount of reducing sugar?
Orange red
35
What is the color of the Benedict’s solution when there are large amount of reducing sugar?
Brick-red
36
A copper reduction test in which heating a mixture of a monosaccharides in a given time interval results in the conversion of cupric ions in the reagent to cuprous ions with the formation of copper (I) oxide seen as a brick red precipitate in the mixture
Barfoed Test
37
Copper reduction in Barfoes’s test occurs in an
Acidic medium (pH 4.6)
38
In Barfoed test when red precipitate is formed faster what is present?
Monosaccharides
39
In Barfoed test when red precipitate is formed slower what is present?
Disaccharide
40
Also known as silver mirror test
Tollen’s test
41
Sugars with ________ are capable reducing Tollen’s reagent
Aldehyde groups
42
What is the Tollen’s reagent?
Ammoniacal solution of silver
43
What is the color of a positive result Tollen’s test?
Gray - black precipitate (silver mirror)
44
Reducing sugars that reduce silver ions in the test reagent to elemental silver
Glucose & lactose
45
Common dietary monosaccharides
Glucose Galactose Fructose
46
Examples of Pentose
Ribose & cellobiose
47
2 Examples of Pentose
Ribose & cellubiose
48
4 Examples of hexoses
Glucose, fructose, galactose, maltose
49
Most important sugars
Pentoses & hexoses
50
3 Examples of aldehyde
Glucose, maltose, galactose
51
Example of ketone
Fructose
52
Molisch test is based on dehydration by ____
Sulfuric acid