Ch. 5 Flashcards
(28 cards)
Study of measuring the amount of heat absorbed or released during a chemical reaction or a physical change.
Thermochemistry
Device designed to measure the energy change for processes occurring under conditions of constant volume; commonly used for reactions involving solid and gaseous reactants or products.
Bomb calorimeter
Unit of heat or other energy
Calorie (cal)
Device used to measure the amount of heat absorbed or released in a chemical or physical process.
Calorimeter
Process of measuring the amount of heat involved in a chemical or physical process.
Calorimetry
Chemical reaction or physical change that absorbs heat.
Endothermic reaction
Sum of a system’s internal energy and the mathematical product of its pressure and volume.
Enthalpy (H)
Chemical reaction or physical change that releases heat.
Exothermic reaction
Internal energy of a system changes due to heat flow in or out of the system or work done on or by the system
1st law of thermodynamics
Transfer of thermal energy between two bodies.
Heat (q)
Extensive property of a body of matter that represents the quantity of heat required to increase its temperature by 1 degree Celsius (or 1 kelvin)
Heat capacity (C)
If a process can be represented as the sum of several steps, the enthalpy change of the process equals the sum of the enthalpy changes of the steps.
Hess’s Law
Compound composed only of hydrogen and carbon; the major component of fossil fuels.
Hydrocarbon
Total of all possible kinds of energy present in a substance or substances.
Internal energy (U)
Energy of a moving body, in joules, equal to 1/2mv^2
Kinetic energy
Unit used for quantifying energy provided by digestion of foods.
Nutritional calorie (Calorie)
Energy of a particle or system of particles derived from relative position, composition, or condition.
Potential energy
Intensive property of a substance that represents the quantity of heat required to raise the temperature of 1 gram of the substance by 1 degree Celsius
Specific heat capacity (c)
Heat released when one mole of a compound undergoes complete combustion under standard conditions.
Standard enthalpy of combustion
Enthalpy change of a chemical reaction in which 1 mole of a pure substance is formed from its elements in their most stable states under standard conditions.
Standard enthalpy of formation
Set of physical conditions as accepted as common reference conditions for reporting thermodynamic properties.
Standard state
Property depending only on the state of a system , and not the path taken to reach that state.
State function
All matter other than the system being studied.
Surroundings
Portion of matter undergoing a chemical or physical change being studied.
System