CH622 - Electronic Spectrae of Complexes

Question 1

Answer 1

Question 2

Answer 2

Question 3

Answer 3

Question 4

Answer 4

Question 5

Answer 5

Question 6

שונים/אותו הדבר?
הסבר הגורם לכך?

Answer 6

Question 7

Answer 7

Question 8

Answer 8

Question 9

Answer 9

Question 10

Answer 10

Question 11

Electronic transitions between states with different spin multiplicities.

Answer 11

Spin Forbidden

Question 12

Ground state will have the _____spin multiplicity.

Answer 12

Largest

If thesame spin multiplicity, then the GS will have the highest value of L.

Question 13

In O_h and D_4h , all d orbitals are gerade and so too are the states arising from their d configurations. Thus, their electronic transitions between them are________.

Answer 13

Laporte Forbidden​

Question 14

If a system is centrosymmetric, electronic transitions between states with the same inversion symmetry (g –> g, u –> u) are forbidden, but transitions between states of different inversion symmetry

(g –> u, u –>g) are allowed.

Answer 14

Laporte’s Rule​

Question 15

Idenifty the gaseous ground state term symbol for a d² metal ion.

Answer 15

^{<strong>3</strong>}F

Question 16

Idenifty the strong field region of the

d⁵ Tanabe-Sugano Diagram.

Answer 16

Low Spin Configurations

Question 17

Idenifty the weak field region of the

d⁵ Tanabe-Sugano Diagram.

Answer 17

High Spin Configurations

Question 18

Determine M_L and M_S vaules of the free ions term below:

²D

Answer 18

D: L=2 M_L={-2,-1,0,1,2}

2S+1=2 –> S=1/2 –> M_S= {1/2,-1/2}