CH623 - Charge Transfers and Selection Rules Flashcards
Revise theoretical background. (22 cards)
1
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2
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3
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4
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5
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6
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7
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8
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9
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10
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11
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12
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13
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14
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15
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16
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17
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18
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19
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20
Q
Intensity (ϵ) for spin-forbidden and Laporte forbidden transitions?
A
10-3 < ϵ < 1
21
Q
Intensity (ϵ) for spin-allowed and Laporte forbidden transitions?
A
1 < ϵ < 100
or
100 < ϵ < 1000
100 < ϵ < 1000 for low symmetry Oh complex or square planar complex with organic ligands.
22
Q
Intensity (ϵ) for spin-allowed and Laporte allowed transitions?
A
100 < ϵ < 106