CH623 - Charge Transfers and Selection Rules Flashcards

Revise theoretical background. (22 cards)

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20
Q

Intensity (ϵ) for spin-forbidden and Laporte forbidden transitions?

A

10-3 < ϵ < 1

21
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Intensity (ϵ) for spin-allowed and Laporte forbidden transitions?

A

1 < ϵ < 100
or
100 < ϵ < 1000

100 < ϵ < 1000 for low symmetry Oh complex or square planar complex with organic ligands.

22
Q

Intensity (ϵ) for spin-allowed and Laporte allowed transitions?

A

100 < ϵ < 106