Chapter 1 Flashcards
(9 cards)
Halides
Halogen is group 7 on the periodic table
Halides are halogen atoms with a negative charge
Fluoride Astatide Chlorine Bromide Iodine
What are the common atoms found in organic chem?
Carbon
Hydrogen
Oxygen
Nitrogen
And the halides
What holds together most organic compounds?
Covalent Bonds
- The sharing of an electron
What is the octet rule?
Commonly the reactions go in a way to achieve the electron configuration of the nearest noble gas.
Trying to reach 8 electrons.
What is a hybrid orbital?
In organic molecules the orbitals of the atoms are combined to form hybrid orbitals.
Consisting of S&P orbitals
Bonding
Sigma Bonds
Pi Bonds
Sigma bonds
- Single bonds - Those in which the electron density is between the nucli
- Symmetrical about the axis
- Can freely rotate
Pi Bonds overlap above and below the plane of the atoms.
How multiple bonds effect a bond?
Multiple bonds create a barrier to free rotation about the axis of the bond.
- means the molecule is more rigid.
As a rule more bonds decrease the bond length.
More bonds means more energy to break bonds.
Delocalised electrons
Delocalisation of an electron occurs when the valance electrons of an atom does not stay in its shell + starts to move around freely in valance shells of its covalently bonded molecules
Resonance
A method of describing the delocalised electrons in some molecules where the bonding can not be explicitly expressed by a single lewis structure.