Chapter 1-Structure and Bonding Flashcards

1
Q

Organic chem

A

Study of carbon compounds

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2
Q

Why is carbon so important

A

-can share 4 valence electrons
-forms four strong covalent bonds
-can form a chain

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3
Q

Shape of s orbital

A

Sphere

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4
Q

Shape of p orbital

A

Dumbbell

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5
Q

Shape of d orbital

A

Clover leaf

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6
Q

Law of aufbau

A

Lowest energy filled first

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7
Q

Law of paul

A

One arrow up and one arrow down on each

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8
Q

Law of hunds

A

One arrow on each line before adding a second to the first one

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9
Q

Sp shape

A

180
Linear

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10
Q

Sp2 shape

A

120
Trigonal planar

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11
Q

Sp3 shape

A

Tetrahedral

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12
Q

Atomic number

A

= number of protons = number of electrons

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13
Q

Mass number

A

Total of protons and neutrons

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14
Q

Isotopes

A

Atoms with same atomic number but different mass numbers

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15
Q

Wave equation

A

Is the orbital and behavior of electrons and the space they like to be in

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16
Q

Electron shells

A

Layers of electrons orbiting around the nucleus at different energy levels

17
Q

Node

A

The space in between orbitals containing no electron density

18
Q

Ground-state electron configuration

A

Lowest energy arrangements with s p d levels with arrows

19
Q

Ionic bond

A

A bond between elements where an electrons is transferred

20
Q

Covalent

A

Share electrons

21
Q

Molecule

A

Neutral collection of atoms held together by covalent bonds

22
Q

Lewis structure

A

Electron dot structures
-indicates covalent bonds

23
Q

Kekule structures

A

Line-bind structure
-line instead of dot

24
Q

Why can Sp3 orbitals form stronger bonds than unhybridized s or p orbitals

A

1 or 2 orbitals are larger and can overlap more effectively

25
Tetrahedral angle
109.5
26
Bond length and strength relationship
As bond length increases, bond strength weakens
27
Condensed structures
CH3CH2CH3
28
Skeletal structures
Carbons and their hydrogens are not drawn. Lines and bends
29
Molecular formula
Number of each atoms in a compound
30
Valence Bond theory
Electron sharing occurs when two orbitals overlap
31
Sigma bonds
Have a circular cross section and are formed by head on interaction
32
Pi bonds
Formed by sideways interaction of p orbitals
33
Sp3 carbons
Only forming single bonds with tetrahedral geometry
34
Sp2 carbons
Forming one double bond with planar geometry
35
Sp carbon
Forming a triple bond with linear geometry