Chapter 10 - Structure and Nomenclature of Organic Compounds Flashcards

1
Q

organic molecules

A

compounds containing carbon atoms linked to each other, and to other non-metallic atoms by covalent bonds

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2
Q

saturated molecule

A

single bonds only

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3
Q

unsaturated molecule

A

one or more carbon to carbon double or triple bonds

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4
Q

hydrocarbon

A

compound that contains carbon and hydrogen only

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5
Q

molecular formula

A

gives actual number and type of atoms present in molecule

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6
Q

structural formula

A

represents 3D arrangement of atoms in a molecule

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7
Q

semistructural formula

A

condensed formula that summarises structural formula in single line

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8
Q

isomers

A

molecules that contain the same number and type of atoms, arranged in different ways

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9
Q

structural isomers

A

have the same molecular formulas of atoms in a molecule.

chain and positional

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10
Q

chain isomers

A

difference in the branching of the hydrocarbon chain

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11
Q

positional isomers

A

functional group in a different location on the carbon chain

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12
Q

stereoisomers

A

isomer where atoms in 2 molecules are connected in same order, but have different arrangements.
optical and geometric

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13
Q

optical isomers

A

different placement of groups around one atom in a molecule

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14
Q

chiral

A

not superimposable on its mirror image.

no plane of symmetry

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15
Q

chiral centre

A

carbon atom attached to 4 different groups

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16
Q

enantiomers

A

pair of chiral molecules

17
Q

geometric isomers

A

occurs when theres restricted rotation in molecule.
carbon to carbon double bond.
cis and trans

18
Q

cis isomers

A

groups on same side.

longest alkyl group attached to same side of double bond

19
Q

trans isomers

A

groups on opposite sides.

longest alkyl groups attached to opposite sides of double bond

20
Q

homologous series

A

series of organic compounds in which each member of the group differs from the previous member by a -CH2 unit

21
Q

alkanes

A

hydrocarbons with only single bonds.
non-polar.
saturated.
CnH2n+2

22
Q

cyclohexane

A

carbon atoms formed in a ring (cyclic)

23
Q

cyclic molecules

A

molecule that form rings

24
Q

alkenes

A

hydrocarbons that contain a carbon-carbon double bond.
non-polar.
unsaturated.
CnH2n

25
alkynes
hydrocarbons that contain carbon-carbon triple bonds. unsaturated. CnH2n-n
26
benzene
unsaturated cyclic hydrocarbon molecule. C6H6. 4th electron is delocalised around all carbons
27
functional group
atom or group of atoms in organic molecules that largely determines the molecules properties and reactions
28
haloalkanes
derived from alkanes, in which a hydrogen atom is replaced with a halogen atom
29
alcohols
contain the hydroxyl (-OH) group
30
primary alcohol
carbon bonded to the -OH group is only attached to one alkyl group
31
secondary alcohol
carbon bonded to the -OH group is also bonded to two alkyl groups
32
tertiary alcohol
carbon bonded to the -OH group is also bonded to three alkyl groups
33
primary amines
contains the amino (-NH2) functional group
34
aldehydes
contains the carbonyl (C=O) group bonded to a hydrogen on one end of the molecule. recognised by presence of -CHO group at one end on structural formula
35
ketones
contains the carbonyl functional group (C=O) within carbon chain
36
carboxylic acid
contain the carboxyl group (-COOH). | always located at end of chain
37
amides
``` contains the (-CONH-) group. always located at end of chain ```
38
esters
``` contain ester (-COO-) group. located within chain ```