Chapter 11 Flashcards

1
Q

The problem with drinking seawater

A

difference in salinity in red blood cells, cells dehydrate, shrivel, and die

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2
Q

Semipermeable membrane

A

channels through which water flows

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3
Q

Osmosis

A

spontaneous migration of water through semipermeable membrane

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4
Q

How does water move

A

from high concentration of water (low solute) to low concentration of water

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5
Q

Hypertonic

A

a solution containing a higher concentration of solutes than inside a red blood cell
the cell shrinks

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6
Q

Isotonic

A

a solution that matches the concentration of solutes in cells - no change in cell

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7
Q

Hypotonic

A

a solution that contains a lower concentration of solutes than inside cell - cell expands

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8
Q

the pressure applied across a semipermeable membrane to stop the flow of water from te compartment containing pure solvent or a less conentrated solution to the compartment containing a more concentrated solution

A

omotic pressure

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9
Q

osmotic pressure formula

A

P = MRT

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10
Q

Explain P = MRT

A
M = total molar concentration
R = gas law constant
T = absolute temperature
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11
Q

Characteristics of solutions that depend upon the concentration and not the identity of the particles dissloved in the solvent

A

colligative property

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12
Q

Osmotic pressure when ion pair is involved

A

P = iMRT

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13
Q

a process that involves removing most of the ions from seawater

A

desalination

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14
Q

reverse osmosis

A

distillation

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15
Q

a purification process in which solvent is forced through semipermeable membranes, leaving dissolved impurities behind

A

distillation

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16
Q

the amount of energy required to convert a solid into a liquid

A

enthalpy (heat) of fusion (∆Hfusion)

17
Q

the amount of energy required to convert a liquid into a gas

A

enthalpy (heat) of vaporization (∆Hvap)

18
Q

the partial pressure of a gas in equilibrium with liquid at a contant temperature

A

vapor pressure

19
Q

the pressure exerted by a gas in equilibrium with its liquid phase at a given temperature

A

vapor pressure

20
Q

having a significant vapor pressure at a given temperature

A

volatile

21
Q

the higher the vapor pressure…

A

the more volatile

22
Q

Raoult’s law

A

P1 = X1 P°1

23
Q

Raoult’s law: P1

A

vapor pressure of solvent over the solution

24
Q

Raoult’s law: X1

A

mole fraction of the solvent

25
Q

Raoult’s law: P°1

A

vapor pressure of pure solvent

26
Q

the presence of solute particles…

A

lowers the vapor pressure of the water in seawater

27
Q

Boiling point elevation

A

ΔTb = Kb msolute

28
Q

Freezing point lowering

A

ΔTf = Kf msolute

29
Q

what does molality equal

A

moles of solute / kg of solvent

30
Q

When using boiling point elevation and freezing point lowering for ions…

A

include van’t Hoff factor (i)

31
Q

Henry’s law

A

C gas = kH x Pgas

32
Q

C gas

A

the maximum concentration of gas in a particular solvent

33
Q

k H

A

Henry’s law constant for teh gas

34
Q

P gas

A

the partial pressure of the gas in the solvent