Chapter 12 - Redox reactions Flashcards

1
Q

define redox reaction

A

reaction where both oxidation and reduction takes place

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2
Q

define oxidising agent

A

assists other substances to oxidise

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3
Q

define reducing agent

A

assists other substances to reduce

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4
Q

table for OXIdation

A

OXYgen (+)
OXYdising agent (+)
hydrogen (-)
electrons (-)

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5
Q

common non redox reactions

A
  • neutralisation
  • decomposition
  • double displacement
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6
Q

common redox reactions

A
  • single displacement
  • combustion
  • synthesis
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7
Q

test for oxidising agent and observations

A

add aqueous potassium iodide
= potassium iodide turns from colourless to brown

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8
Q

test for reducing agent and observations

A

add acidified potassium manganate
= acidified potassium manganate turns from purple to colourless

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9
Q

examples of oxidising agents (4)

A
  • acidified potassium manganate
  • halogens
  • oxygen
  • acidified potassium dichromate
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10
Q

examples of reducing agents (5)

A
  • aqueous potassium iodide
  • carbon monoxide
  • carbon
  • group one metals and hydrogen - sulfur dioxide
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11
Q

examples of both oxidising and reducing agent

A

water and hydrogen peroxide

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12
Q

observation when oxidising agent is being reduced

A

acidified purple potassium manganate turns colourless

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13
Q

observation when reducing agent is being reduced

A

colourless potassium iodide turns brown

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14
Q

element / compound rule for oxidation

A

0

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15
Q

ion rule for oxidation

A

see charge of ion

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16
Q

hydrogen rule for oxidation

17
Q

oxygen rule for oxidation

18
Q

transition metal rule for oxidation

A

see roman letter

19
Q

group 1 elements rule for oxidation

20
Q

group 2 elements rule for oxidation

21
Q

group 3 elements rule for oxidation

22
Q

rules in calculating oxidation state

A

the total has to be zero and individual elements can be solved with the rules

23
Q

4 types of doing redox reactions

A
  • oxygen transfer
  • hydrogen transfer
  • electrons transfer
  • oxidation state
24
Q

explanation for oxidation in oxygen transfer

CuO + H2 = Cu + H2O

A

CuO + H2 = Cu + H2O
= hydrogen has become oxidised
= it gained oxygen to become water
= copper (ll) oxide is the oxidising agent

25
explanation for oxidation hydrogen transfer 2HCl + F2 = 2HF + Cl2
2HCl + F2 = 2HF + Cl2 = hydrochloric acid has become oxidised = it lost hydrogen to become chlorine gas = fluorine is the oxidising agent
26
explanation for oxidation electrons transfer Zn + Cu2+ = Zn2+ + Cu
Zn + Cu2+ = Zn2+ + Cu = zinc metal has been oxidised = it lost two electrons to become Zinc ion = copper ion is the oxidising agent
27
explanation for oxidation oxidation state K + NaCl = KCl + Na
K + NaCl = KCl + Na = potassium has been oxidised = its oxidation state increased from o in K to +1 in KCl = sodium chloride is the oxidising agent
28
explanation for reduction in oxygen transfer CuO + H2 = Cu + H2O
CuO + H2 = Cu + H2O = copper (ll) oxide has been reduced = it lost oxygen to become copper metal = hydrogen is the reducing agent
29
explanation for reduction hydrogen transfer 2HCl + F2 = 2HF + Cl2
2HCl + F2 = 2HF + Cl2 = fluorine has been reduced = it gained hydrogen to become hydrogen fluoride = hydrochloric acid is the reducing agent
30
explanation for reduction electrons transfer Zn + Cu2+ = Zn2+ + Cu
Zn + Cu2+ = Zn2+ + Cu = copper ion has been reduced = it gained 2 electrons to become copper metal = Zn is the reducing agent
31
explanation for reduction oxidation K + NaCl = KCl + Na
K + NaCl = KCl + Na = Sodium chloride is being reduced = its Oxidising agent decreased from +1 in NaCl to 0 in Na = potassium is the reducing agent
32
theory : how to test for reducing agent like SO2
use acidifies potassium manganate (Vll), place on a filter paper and if gas evolved turns purple potassium manganate (Vll) colourless, gas is sulfur dioxide
33
theory : how do you test for oxidising agent like F2
use aqueous potassium iodide and bubble gas evolved through KI if it turns colourless potassium iodide brown, the gas is a halogen
34
theory : explain how potassium iodide can be used to test for an oxidising agent
When colourless aqueous potassium iodide is added to added to an oxidising agent, it turns brown due to iodine solution produced