chapter 16 vocabulary Flashcards
(25 cards)
single covalent bond
a bond in which 2 atoms share a pair of electrons
structural formulas
chemical formulas that show the arrangement of atoms in molecules and polyatomic ions
double covalent bonds
bond that involve 2 shared pairs of electrons
triple covalent bonds
bonds that are/involve 3 shared pairs of electrons
coordinate covalent bonds
a covalent bond in which one atom contributes both bonding electrons
bond dissociation energy
the total energy required to break the bond between 2 covalently bonded atoms
resonance structures
structures that occur when it is possible to write 2 or more valid electron dot formulas that have the same number of electron pairs for a molecule
diamagnetic
substances in which all of the electrons are paired (weakly repelled by an external magnetic field)
paramagnetic
substances that contain one or more unpaired electrons
molecular orbitals
when 2 atoms combine, this model assumes that their atomic orbitals overlap to produce…(orbitals that apply to entire molecules)
bonding orbital
a molecule orbitals with an energy that is lower than that of the atomic orbitals from which it formed
anti bonding orbital
the other molecular orbital who’s energy is higher than that of the atomic orbitals from which it formed
sigma bond
when 2 atomic orbitals combine to form a molecular orbital that is symmetrical along the axis connecting 2 atomic nuclei
tetrahedral angle
all angles = 109.5
VESPR theory
states that because electron pairs repel, molecular shape adjusts so the valence electron pairs are as far apart as possible
non polar covalent bond
when the atoms in the bond pull equally (as occurs when like atoms are bonded). the bonding electrons are shared equally
polar covalent bond
when a covalent bond joins two atoms of different elements and the bonding electrons are shared unequally
polar molecule
one end of the molecule is slightly negative and the other end is slightly positive
dipole
a molecule/s that has 2 poles
Van der Waals forces
the weakest attractions, 2 types
dispersion forces and dipole molecules
dispersion forces
the weakest of all molecular interactions are cause by the motion of electrons
dipole interactions
occurs when polar molecules are attracted to one another
hydrogen bonds
attractive forces in which a hydrogen covalently bonded to a very electronegative atom is also weakly bonded to an unshared pair of electrons of another electronegative atom
network solids
(most are very stable substances), solids in which all of the atoms are covalently bonded to each other