Chapter 17.2 Flashcards

0
Q

Entropy and rxn tendency

Symbol and unit

A

Measure of disorder or randomness of particles In a system
Symbol is change S
S=Sp-Sr
Units are KJ/mol K

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1
Q

Enthalpy and Rxn tendency

A

Most rxns in nature are Exothermic
Produce low NRG, stable products
Rxn proceed spontaneously

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2
Q

Who has the greatest entropy btw solids liquids and gases

A

S Solid<S gas

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3
Q

When are rxns favored to occur and where does nature go towards

A

When S increases

High disorder: results in low enthalpy and high entropy

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4
Q

Why do reactions happen

A

1 favored by entropy

2 favored by enthalpy (low heat)

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5
Q

Which matters more entropy or enthalpy

A

Depends on T

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6
Q

Define Gibbs free NRG and give symbols

A

A value used to predict whether ChangeH or ChangeS will determine rxn tendency
ChangeG KJ/Mol

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7
Q

What is the equation for Gibbs free NRG and another name

A

Change H - TChange S

Thermal dynamic eqn

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8
Q

What does Change G mean

A

Measures the combined effects of H and S at a specific T
If G is a - value rxn is spontaneous (exergonic)
If G is + rxn is non spontaneous (endergonic)

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9
Q

What if G is 0

A

Equilibrium

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