Chapter 2: Atomic Structure and Interatomic Bonding Flashcards

1
Q

Mass of Electrons:

A

9.11 x 10 ^-31 kg

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2
Q

Mass of Protons / Neutrons

A

1.67 x 10 ^ - 27 kg

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3
Q

Atomic Number

A

Protons in nucleus of atom = # of electrons in neutral species

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4
Q

Atomic Mass Unit (AMU)

A

1 / 12 the mass of 12C

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5
Q

Atomic Weight

A

Wt of 6.022 x 10 ^23 molecules of atoms

1 amu / atom = 1 g / mol

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6
Q

Electron Behavior

A

Wave-like / particle-like characteristics

Probability of electron’s being at various locations around the nucleus

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7
Q

Energy States

A

Electrons have discrete energy states

Tend to occupy the lowest available energy state

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8
Q

Electron configuration in most elements

A

Not stable; Valence (outer) shell usually not filled completely

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9
Q

Quantum Numbers

A

Characterization of electrons in an atom through 4 parameters

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10
Q

4 Parameters of Quantum Numbers

A

Principle Quantum Number (n)

Angular momentum ( I)

Magnetic (m)

Spin (s)

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11
Q

Principle Number (n)

A

Distance from nucleus

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12
Q

Angular Momentum (I)

A

Shape of Orbital

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13
Q

Magnetic (m)

A

Orientation in space

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14
Q

Spin (s)

A

Electron Spin

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15
Q

Pauli Exclusion Principle

A

Each energy level can only hold no more than two electrons of opposite spin

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16
Q

Ionic Bond

A

Metal + Nonmetal

Metal donates electrons, while nonmetal accepts electrons

Requires electron transfer

17
Q

Energy in Ionic Bonding:

A

Minimum energy is the most stable.

Balance of attractive and repulsive terms

18
Q

Net Energy for Ionic Bonding Formula (En)

A

Ea + Er = (- A / r) + (B / r^n)

Ea: Attractive energy
Er: Repulsive Energy
r: Interatomic separation

19
Q

Covalent Bonding

A

Similar electronegativity

Share electrons

Bonds determined by valence - S & p orbitals

20
Q

Primary Bonding

A

Metallic Bond

Ionic-Covalent Mixed Bonding

21
Q

% Ionic Character

A

(1 - e ^ -((xa - Xb)^2/4) x 100%

Xa and Xb are Pauling electronegatives

22
Q

Secondary Bonding

A

Interaction between dipoles

Permanent dipoles molecule induced

23
Q

Details of Ionic Bonds

A

Large bond energy

Nondirectional

Ceramics

24
Q

Details of Covelent Bonding

A

Variable Bond Energy

Directional

Semiconductors, ceramics, polymer chains

25
Q

Details of Metallic Bonding

A

Variable Bond Energy

Nondirectional

26
Q

Secondary Bonding

A

Smallest Bond Energy

Directional

Inter-chain

Inter-molecular