Chapter 2: Physical properties and attractive forces Flashcards
(14 cards)
The physical properties of ionic compounds and their bonds
Forces: Ion-Ion
Melting point: high
Boiling point: high
What are ion-ion forces?
strong differences in electronegativity. Highest form of forces
IMF Vaan der waal forces? what are three different types?
Dipole- Dipole forces: for organic molecules with a uneven disruption of bonding electrons (highly polarized) . Molecules arrange themselves to where they the positive end is directed to negative.
Hydrogen bonding: hydrogen bonded to NOF. They are weaker bonds than normal covalent bonds but stronger than dipole-dipole
LDF: Small temporary charges. The strength of the pull depends on surface area and the shells an atom have
How to determine the force of LDF?
Surface area: The flatter, the longer, the spherical the greater the pull
Shells: the more shells the greater the pull
What factors effect boiling point
- strength of LDF
- Molecule weight
- Surface Area
What are the general rules of solubility psychically?
- Polar and ionic solids are usually soluble in polar solvents.
- Polar liquids are usually miscible.
- Nonpolar solids are usually soluble in nonpolar solvents.
- Nonpolar liquids are usually miscible.
- Polar and nonpolar liquids, like oil and water, are usually not soluble to large extents.
Guidelines for water solubility?
For a compound that is hydrophllic:
* Compounds with one to three carbon atoms are water soluble.
* Compounds with four or five carbon atoms are borderline.
* Compounds with six carbon atoms or more are insoluble.
Rank the strength of all forces:
cation-anion: very strong
Covalent bond: strong
Ion-dipole: Moderate
Dipole-Dipole: weak
Edited: Van der waals forces
nonpolar covalent bonds
Edited: Van der waals forces
nonpolar covalent bonds
Edited: dipole-dipole
polar covalent bonds check if there is a dipole moment.
Edited: Ion-Ion
Atoms with different formal charges
Edited: Rank the forces from highest melting point to lowest
- ion-ion
- Hydrogen bonding
- dipole-dipole
- Van deer waals
Edited: The larger the atom the blank the van deer waal forces
stronger