Chapter 3 Book Flashcards

1
Q

Heteroatoms

A

atoms that are not C or H

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2
Q

Functional groups

A

determine molecules geometry, physical properties, and reactivity

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3
Q

Carbon Backbone

A

C-C and C-H sigma bonds make up skeleton

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4
Q

When are molecules reactive

A

when they have a functional group

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5
Q

Hydrocarbons

A

made of C and H

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6
Q

alkanes

A

only C-C sigma bonds
R-H

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7
Q

Alkenes

A

only C=C

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8
Q

Alkynes

A

C triple bond C

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9
Q

Why are aromatic hydrocarbons called this

A

early known aromatic compounds had strong odor

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10
Q

Primary Carbon

A

1 degree
|
-C-C
|

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11
Q

Secondary Carbon

A

2 degrees
C
|
-C-C
|

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12
Q

Tertiary Carbon

A

3 degrees
C
|
-C-C
|
C

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13
Q

Quaternany Carbon

A

4 degrees
C
|
C-C-C
|
C

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14
Q

How are H Classified

A

Whatever C they are on that is their type too

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15
Q

Primary Hydrogen

A

1 degree
|
H -C-C
|

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16
Q

Secondary Hydrogen

A

2 degrees
C
|
H-C-C
|

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17
Q

Tertiary Hydrogen

A

3 degrees
C
|
-C-C
|
C

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18
Q

R-X

A

Alkyl halide

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19
Q

Halo group

A

Alkyl Halide

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20
Q

R-OH

A

Alcohol

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21
Q

Hydroxy Group

A

Alcohol

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22
Q

R-O-R

A

Ether

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23
Q

Alkoxy group

A

ether

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24
Q

R-NH2

A

Amine

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25
R2NH
Amine
26
R3N
Amine
27
Amino Group
Amine
28
R-SH
Thiol
29
mercapto group
thiol
30
R-S-R
Sulfide
31
Alkylthio group
Sulfide
32
1 degree alkyl halide or alcohol
. | -C-C-Z |
33
2 degree Alkyl halide or alcohol
. C | -C-C-Z |
34
3 degree alkyl halide or alcohol
. C | -C-C-Z | C
35
How are alkyl haildes and alcohols classified?
on number of C bonded to C
36
How are amines classifed?
C-N
37
1 degree amine
. | -C-N- |
38
2 degree amine
. | -C-N- | C
39
3 degree amine
. | -C-N-C | C
40
Carbonyl group
C-O bond
41
. O " R-C-H
Aldehyde
42
. O " R-C-R
Ketone
43
. O " R-C-OR
Ester
44
Carbonyl group
ketone
45
. O " R-C-NH | H
Amide
46
. O " R-C-Cl
Acid Chloride
47
Intermolecular Forces
interactions that exist between molecules
48
Ionic Compounds
oppositely change particle held together by extremely strongly electrostatic interactions Strong
49
Van der waal forces
weak interactions caused by momentary changes in electron density in molecules
50
What force do all molecules have including nonmolecules
Van der Waal
51
polarizability
how electron cloud around atom responds to charges affects VWF
52
What makes a molecule more polarizable
large atoms
53
Dipole-Dipole
attractive forces between permanent dipoles of 2 polar molecules
54
Hydrogen bonding
H atom bonds to O, N, F and is attracted to other O,N,F's
55
Boiling point
Temp where liquid becomes a gas
56
list the intermolecular forces that make the boiling point higher
VWF, D-D, HB, Ionic
57
If you have a larger surface area how does that affect the BP
Higher boiling point
58
If you have a more polarizable atom how does that affect the boiling point
Higher boiling point
59
What is more volatile
a lower boiling point
60
Melting point
Temperature which solid is converted into a liquid
61
If you have strong intermolecular forces what does that do to Melting Point
Higher Melting Point
62
more symmetrical what does that do to the melting point
higher melting point
63
What properties affect the boiling point
Intermolecular forces Surface area Polarizable atoms
64
What properties affect the melting point
Intermolecular force symmeticallism
65
Solubility
like dissolves lik
65
Solubility
like dissolves lik
66
What happens to the solubility of a molecule with size
large= not soluble in H2O
67
If a molecule contains heteroatom, pi bond, or both what happens
electron decfient site on molecule
68
What makes C electrophillic
heteroatom
69
If there is a lone pair on heteroatom what is it
basic and nucleophilic