Chapter 6 Flashcards

1
Q

cells obtain energy from ______ using _______ and apply the energy to ______

A

sugar, cellular respiration, perform work

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2
Q

metabolism

A

totality of an organism’s chemical reactions

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3
Q

metabolism is an emergent property that arises from?

A

orderly interactions between molecules

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4
Q

metabolic pathway

A

begins with specific molecules and ends with a product

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5
Q

each step of the metabolic pathway is?

A

catalyzed by a specific enzyme

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6
Q

catabolic pathway

A

release energy by breaking complex molecules into simpler compounds.

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7
Q

anabolic pathway

A

consume energy to build complex molecules from simpler ones.

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8
Q

anabolic pathway is also called?

A

biosynthetic pathway

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9
Q

bioenergentics

A

study of how energy flows through living organisms.

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10
Q

energy

A

capacity to cause change

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11
Q

work is the movement of?

A

matter against opposing forces

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12
Q

thermal energy

A

kinetic energy associated with random movement of molecules.

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13
Q

heat

A

thermal energy in transfer from one object to another

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14
Q

chemical energy

A

potential energy available for release in a chemical reaction

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15
Q

thermodynamics

A

study of energy transformations

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16
Q

Organisms are ____ systems

A

open

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17
Q

first law of thermodynamics

A

energy cannot be created or destroyed

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18
Q

the first law of thermodynamics is also called?

A

principle of conservation of energy

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19
Q

second law of thermodynamics

A

every energy transformation increases entropy of the universe

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20
Q

heat ____ the disorder of the surroundings

A

increases

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21
Q

scientists use the term disorder to? (2)

A

-show how dispersed energy is in a system
-show how many energy levels are present

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22
Q

spontaneous process occurs without?

A

energy input

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23
Q

For a process to occur spontaneously it must?

A

increase the entropy of the universe

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24
Q

Individual cells and whole organisms create?

A

ordered structures from disorganized starting materiel

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25
free energy
portion of a system's energy that can do work when temp and pressure are constant.
26
A process is spontaneous and can perform work only?
when it is moving towards equilibrium
27
exergonic reaction
proceeds with release of free energy
28
exergonic reaction is ________ and Delta g is _____?
spontaneous, -
29
endergonic reaction
absorbs free energy from its surroundings
30
endergonic reaction is _______ and Delta g is _____?
nonspontaneous, +
31
the magnitude of Delta g is?
the quantity of energy required to drive a reaction
32
Reactions in an isolated system eventually?
reach equilibrium and can do no work.
33
One of the defining features of life
metabolism as a whole is never at equilibrium
34
What prevents a system from reaching equilibrium?
the product of each reaction is the reactant for the next.
35
A cell does 3 main kinds of work.
-chemical -transport -mechanical
36
energy coupling
the use of an exergonic process to drive an endergonic one
37
Most energy coupling in cells is mediated by?
ATP
38
ATP (adenosine triphosphate) is composed of
ribose, adenine,and a chain of 3 phosphate groups
39
the bonds between the phosphate groups of ATP can be broken by?
hydrolysis
40
ATP hydrolysis releases?
energy, ADP, and inorganic phosphate
41
the energy released during ATP hydrolysis comes from?
chemical changes to a state of lower free energy
42
Why does ATP hydrolysis releases so much energy?
there is a repulsive force from the 3 negatively charged phosphate groups.
43
The triphosphate tail of ATP is the chemical equivalent to?
compressed spring
44
the chemical work in a cell is powered by?
ATP hydrolysis
45
ATP drives endergonic reactions by?
phosphorylation
46
Phosphorylation
transferring a phosphate group to another molecule
47
The recipient molecule from phosphorylation is called?
phosphorylated intermediate
48
Overall the coupled reactions in ATP hydrolysis are?
exergonic
49
ATP hydrolysis leads to? (2)
-change in proteins shape -affects its ability to bond to other molecules
50
The energy to phosphorylate ADP comes from?
catabolic reactions in the cell
51
catalyst
speeds up a reaction without being consumed
52
enzyme
macromolecule that acts as a catalyst
53
most enzymes are ___?
proteins
54
Activation energy
energy required to start a reaction by breaking bonds
55
Instead of relying on heat, organisms carry out _____ to speed up reactions.
catalysis
56
Enzymes do not affect?
the change in free energy (Delta G)
57
Enzymes are ____ for the reactions they catalyze?
specific
58
substrate
reactant molecule on which an enzyme acts
59
Most enzymes names end in?
ase
60
active site
region that the substrate binds to the enzyme
61
Enzyme specificity results from the fit between?
the shape of the active site and substrate
62
Induced fit
substrate binds to an active site and both change shape slightly, creating an ideal fit for catalysis
63
Substrates are held to an enzyme's active site by?
weak interactions
64
example of weak interactions
hydrogen bonds
65
Saturated Enzyme
All enzyme molecules in a solution are bonded with substrate.
66
an enzymes activity can be affected by? (2)
-temperature and pH -chemicals that influence the enzyme
67
Each enzyme has a ______ and ______ at which the reaction rate is the greatest.
optimal temperature, pH
68
Cofactors
carry out processes difficult for amino acids
69
Cofactors are _____ molecules.
non protein
70
Coenzyme
organic cofactor
71
What often act as coenzymes or the raw material coenzymes are made out of?
vitamins
72
competitive inhibitor
binds to the active site and prevents substrate from binding
73
noncompetitive inhibitor
binds to an alternate site causing the active site to change shape.
74
Irreversible enzyme inhibitor examples
poison and toxin
75
under certain circumstances an altered __ might be favorable.
enzyme
76
Allosteric regulation
inhibit or stimulate an enzyme's activity
77
allosteric regulation occurs when
a regulatory molecule binds to a protein at one site but affects the proteins function at another site.
78
the enzyme complex oscillates between?
active and inactive shapes
79
binding of an activator molecule ___ the active shape.
stabilizes
80
cooperativity
binding of one substrate molecule to the active site of one sub unit locking the other sub units in shape
81
feedback inhibition
end product of a metabolic pathway shuts down the pathway
82
feedback inhibition prevents a cell from ______ by _______
wasting chemical energy, synthesizing more product than is needed