Chapter 6 Flashcards

(37 cards)

1
Q

in which ways can light be thought of?

A

waves of energy or packets (particles) of energy. Photons.

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2
Q

what are the shapes of an energy wave called?

A

peaks and troughs and wavelengths

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3
Q

what is the range of all possible frequencies called?

A

Electromagnetic spectrum

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4
Q

def’n wavelength

A

the distance btwn adjacent peaks of an oscillating field

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5
Q

def’n frequency

A

the # of wavelengths that pass a particular point in space over a period of time

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6
Q

there is an inverse relationship between wavelength and _____

A

frequency

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7
Q

longwavelength=freq=energy

shortwavelength=freq=energy

A

low freq low energy

high freq high energy

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8
Q

what do you have to multiply nm by to get m?

A

10^9

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9
Q

quantum de’fn

A

a fixed amount

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10
Q

c=λν definition

A
c= speed of light
λ= lamda, wavelength
ν= nu, frequency
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11
Q

E=hv

A

energy of a photon
E= energy
h= planck’s constant
ν= nu, frequency

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12
Q

monochromatic

A

emit a single wavelength of light

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13
Q

polychromatic

A

produce many wavelengths of light

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14
Q

when do you use a line spectrum?

A

for atoms and molecules. you cannot observe a continuous spectrum

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15
Q

1/λ=(Rh)((1/n1^2)-(1/n2^2))

which constants represent positive intigers?

A

n1 and n2

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16
Q

what was the assumed movement of electrons for the bohr model?

A

they move in a circular orbit around the nucleus

17
Q

another word for orbits (in regard to electron movements)

18
Q

name the state of n=1

name the state of n=>1

A

ground state

excited state

19
Q

what does Bohr’s model calculate?

A

the orbit energy levels

20
Q

in the Bohr’s model, how is energy emitted or absorbed by the electron as it changes from one energy state to another?

A

occurs by absorbing or emitting a photon

21
Q

En=(-2.178x10^-18J)(1//n^2)

what does this represent?

A

Bohr model, energy change between one energy state and another

22
Q

what is the charge of the nucleus for the Bohr model?

23
Q

what charge are the electrons for the Bohr’s models?

24
Q

photons are __________ particles of light

25
what are deficiencies of the Bohr model?
- only works well for hydrogen but not atoms w more than one electron - doesn't address why electrons don't fall into the nucleus
26
what is the Heisenberg uncertainty principle?
it is impossible to know both the exact momentum and location of an electron simultaneously.
27
what is an orbital?
a region where there is a 90-95% chance of finding an electron
28
what does an electron shell refer to?
the size of the orbital
29
as n increases, the orbital is _______.
larger, higher energy
30
ʃ= (for atomic orbitals)
angular momentum quantum number | 0, 1, 2, 3
31
ml = magnetic quantum number. what does this describe?
the 3-d orientation of the orbital
32
what are the three common methods for representing orbitals?
- probability/electron density diagrams - contour representations - radial probability distribution
33
ms = spin magnetic quantum number. | what for? what value
spin of the electron charge. | 1/2 or -1/2
34
PAULI EXCLUSION PRINCIPLE
'no two electrons in an atom can have the same set of four quantum numbers n, l, ml, and ms'
35
aufbau principle
orbitals are filled from lowest to highest energy
36
hund's rule
for degenerate orbitals, the lowest energy is attained by having the maximum number of electrons with the same spin
37
paul exclusion priciple
maximum of 2 electrons per orbital.