Chapter 7 Flashcards

1
Q

is the study of the
relationship between energy and matter.

A

Thermochemistry

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2
Q

is anything that has the capacity to
do work.

A

energy

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3
Q

is a force acting over a distance

A

work

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4
Q

is the flow of energy caused by a difference in temperature between objects.

A

Heat

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5
Q

is energy of motion or
energy that is being
transferred.

A

Kinetic energy

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6
Q

is the energy associated with temperature.

A

thermal energy

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7
Q

is energy that is stored in an object (e.g. bond energy), or energy associated with the position of the object.

A

Potential energy

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8
Q

Energy stored in the structure of a compound is

A

chemical
potential energy.

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9
Q

associated with positions of electrons and nuclei

A

chemical energy

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10
Q

Kinetic energy associated with the flow of electrical charge

A

electrical energy

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11
Q

Kinetic energy associated with energy transitions in an atom

A

Light or radiant energy

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12
Q

Potential energy in the nucleus of atoms

A

nuclear energy

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13
Q

Potential energy due to the structure of the atoms, the
attachment between atoms, the atoms’positions relative to
each other in the molecule, or the molecules’ relative
positions in the structure

A

chemical

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14
Q

states that energy
cannot be created nor
destroyed.

A

law of conservation of
energy

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15
Q

as the material or process within which
we are studying the energy changes within.

A

system

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16
Q

as everything else with which the system can exchange energy.

A

surroundings

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17
Q

is the study of the exchange of energy
between the system and the
surroundings.

A

thermochemistry

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18
Q

that the amount of
energy gained or lost by the system has to be equal to the amount of energy lost or gained by the surroundings.

A

conservation of energy

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19
Q

is the amount of energy needed to
move a 1 kg mass a distance of 1 meter.

A

joule (J)

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20
Q

is the amount of energy needed to
raise the temperature of one gram of water 1 o C.

A

calorie (cal)

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21
Q

is the study of energy and its
interconversions.

A

thermodynamics

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22
Q

conversion for calorie to joules

A

1 calorie = 4.184 joules

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23
Q

what is the other name for the law of conservation of energy

A

The First Law of Thermodynamics

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24
Q

of a system is the sum of the kinetic and potential energies of all of the particles that compose the system.

A

internal energy (E)

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25
is a mathematical function whose result only depends on the initial and final conditions, not on the process used.
state function
26
the height from the base to the peak of the mountain is a state function
altitude
27
When energy flows out of a system, E system is
negative
28
When energy flows into the surroundings, E surroundings is
positive
29
Heat exchange at constant pressure is called the
enthalpy
30
are a “graphical”way of showing the direction of energy flow during a process.
Energy diagrams
31
Energy is exchanged between the system and surroundings through
heat and work
32
symbol for heat energy
q
33
symbol for work energy
w
34
is the heat capacity.
C
35
what does the heat of capacity of an object depend on
the mass and the type of material
36
is the amount of heat energy required to raise the temperature of one gram of a substance 1 degree C.
specific heat capacity
37
is the amount of heat energy required to raise the temperature of one mole of a substance 1 degree C.
molar heat capacity
38
what is work caused by?
a change in volume against an external pressure
39
a chemical reaction occurs open to the atmosphere under conditions of what?
constant pressure
40
Heat exchange at constant pressure is called the
enthalpy
41
device used to measure enthalpy
the coffee-cup caloriemeter
42
of a system is defined as the sum of the internal energy of the system (E) and the product of pressure (P) and volume (V):
enthalpy (h)
43
what is the symbol for enthalpy
H
44
Hand Ehave the largest difference for reactions that produce or use what
large quantities of gas.
45
the products of the reaction have less chemical potential energy than the reactants.
exothermic reaction,
46
what does a negative delta h mean?
exothermic reaction
47
what does a positive delta h mean?
endothermic reaction
48
where does the extra thermal energy come from?
the conversion of some of the chemical potential energy in the reactants into kinetic energy in the form of heat.
49
The enthalpy change in a chemical reaction is an
extensive property
50
The surrounding area is called a
bomb calorimeter
51
device used to measure delta E
the bomb calorimeter
52
why is the the bomb calorimeter used?
bc it has a constant volume system
53
is the amount of heat absorbed by the calorimeter for each degree rise in temperature
the heat capacity of the calorimeter
54
heat capacity of the calorimeter
calorimeter constant.
55
As something rolls on the table, some of the energy is converted to heat by
friction
56
is the exchange of thermal energy between a system and surroundings.
heat
57
Heat exchange occurs when system and surroundings have a what?
difference in temperature.
58
is the measure of the thermal energy within a sample of matter.
temperature
59
Heat flows from matter with high temperature to matter with low temperature until both objects reach the same temperature.
Thermal equilibrium
60
heat flows from the material at the ? temperature to the material at the ? temperature.
higher to lower
61
Heat flows until both materials reach the same final temperature –
Thermal Equilibrium
62
The amount of heat energy lost by the hot material equals what?
the amount of heat gained by the cold material.
63
the change in enthalpy for a stepwise process is the sum of the enthalpy changes of the steps
Hess's Law
64
is the enthalpy change when all reactants and products are in their standard states.
standard enthalpy change for a reaction