Chapter 7 Formulae + Constants Flashcards
(35 cards)
Orbital constant // Bohr’s Constant
2.178 E-18
Speed of light (IN VACUUM)
3.00 E8
Planck’s constant
6.626 E-34
Rydberg Constant
1.097 E-7
Formula for wavelength using speed, mass and planck constant
WVL = h/mv
Formula for speed of light (IMP)
C = WVL x Freq.
Formula for emission of energy
DELTA E = hv (planck x frequency)
Formula for wavelength using emission of energy
WVL = hc/DELTA E
Trick for calculation of photon emission (n-n)
Absorption: Bottom - top (B= + )
Emission: Top - Bottom (B= - )
Formula for energy of an electron at a given shell
En = -B(Z^2/n^2)
How to find L
[0, n-1]
How to find ml
[-l,+l]
How to find number of orbitals per shell
n^2
How to find number of electrons per shell
2n^2
n=1 corresponds to
S orbitals
n=2 corresponds to
P orbitals
n= 3 corresponds to
D orbitals
n=4 corresponds to
F orbitals
After n=4 what pattern do orbital letters follow
They are alphabetical (n=4=F, n=5=G, n=6=H)
Heisenberg Uncertainty Principle
DelX x Del(mv) ⩾h/4pi
Relationship between frequency and wavelength
Greater wavelength = lower frequency
Relationship between frequency and energy
Greater frequency = greater energy
Relationship between wavelength and energy
larger wavelength = lower energy
Relationship between colour and energy
Visible light is between ultraviolet and infrared: Violet to red means increasing wavelength, decreasing energy, decreasing frequency