chapter 8 Flashcards

1
Q

what is metallic bonding?

A

strong electrostatic attraction between metal cations and delocalised electrons

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2
Q

what are the properties of metals?

A

high electrical conductivity when solid and molten
high melting and boiling points
insoluble

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3
Q

what is the structure of simple molecular lattices?

A

strong covalent bonds between atoms in molecules
weak intermolecular forces between molecules

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4
Q

what is the structure of giant covalent lattices?

A

atoms held together by network of strong covalent bonds

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5
Q

whats the test for carbonates?

A

add dilute nitric acid
carbonates react to form CO2
if presents then bubbles of gas form

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6
Q

whats the test for sulfates?

A

add barium nitrate
white precipitate forms (barium sulfate)

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7
Q

what is the test for halide ions?

A

add silver nitrate solution

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8
Q

what are the positive results for the halide test?

A

chlorine - white
bromine - cream
iodine - yellow

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9
Q

what halide ion is soluble in dilute ammonia?

A

chlorine

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10
Q

what halide ion is soluble in concentrated ammonia?

A

bromine

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11
Q

what halide ion is not soluble in any ammonia?

A

iodine

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12
Q

what is the order of tests to do?

A

carbonate
sulfate
halides
(silver carbonate or silver sulfate can form)

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13
Q

what is the test for ammonia?

A

add aqueous sodium hydroxide
test gas released with moist pH paper
paper will turn blue

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14
Q

what happens down the group for metal hydroxides (group 2)?

A

increases solubility
pH/alkalinity increases

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15
Q

what is the trend down the group for halogens?

A

reactivity decreases
boiling point increases (increased strength of londons forces due to more electrons

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16
Q

what does a halogen want to do in a reaction?

A

gain an electron
REDUCTION
oxidising agent

17
Q

what is the colour of chlorine in water?

A

pale green

18
Q

what is the colour of bromine in water?

A

orange

19
Q

what is the colour of iodine in water?

A

brown

20
Q

what is the colour of fluorine at RTP?

A

pale yellow gas

21
Q

what is the colour of chlorine at RTP?

A

pale green gas

22
Q

what is the colour of bromine at RTP?

A

red brown liquid

23
Q

what is the colour of iodine at RTP?

A

shiny grey-black solid

24
Q

what is the colour of chlorine when a non-polar solvent (e.g. cyclohexane) is added?

A

layer of pale green

25
Q

what is the colour of bromine when a non-polar solvent (e.g. cyclohexane) is added?

A

layer of orange

26
Q

what is the colour of iodine when a non-polar solvent (e.g. cyclohexane) is added?

A

layer of purple

27
Q

what is disproportionation?

A

redox reaction in which the same element is both oxidised and reduced

28
Q

what are the benefits of chlorine use?

A

kills bacteria present in water to make it safe to drink

29
Q

what are the risks of chlorine use?

A

extremely toxic gas
can react with water to form chlorinate hydrocarbons (suspected carcinogen)

30
Q

what agent are group 2 elements?

A

reducing agents as they gain 2 electrons

31
Q

what is the general equation for the reaction between group 2 elements and oxygen?

A

Mg (s) + 1/2 O2 (g) –> MgO (s)

32
Q

what do group 2 elements form when they react with water?

A

form an alkaline hydroxide
general formula = M(OH)2 and hydrogen gas

33
Q

what is the reactivity trend down the group of group 2 metals?

A

reactivity increases down the group

34
Q

what do group 2 elements form when reacting with a dilute acid?

A

salt and hydrogen
e.g. Mg + 2HCl –> MgCl2 + H2

35
Q

what do group 2 oxides do when they react with water?

A

release hydroxide ions

36
Q

what can group 2 elements be used for in real life?

A

calcium hydroxide added to fields to increase pH of acidic soils
medicine (e.g. indigestion tablets, antacids)