Chemical analysis Flashcards
(28 cards)
What color flame does lithium ion produce
Crimson flame
What color flame does sodium ion produce
Yellow flame
What color flame does potassium ion produce
Lilac flame
What color flame does calcium ion produce
Orange-Red flame
What color flame does Copper ion produce.
Green flame
What are two problems with flame tests?
- The color of the flame can be difficult to distinguish. This could happen due to a low concentration of the metal compound.
- Another reason is the sample could contain a MIXTURE of ions which mask the color of the flame
What is a better test than a flame test
A flame emission spectroscopy
How does an FES work
and the purpose
A sample of the metal ion in solution is placed in a flame
The light given out is then passed into a machine called a spectroscope
The spectroscope converts the light into a line spectrum
Since the positions of the lines in the spectrum are specific for a given metal ion.
So we can use this to identify the metal ion in the sample.
What two things does FES do
To identify the metal ion in the sample.
Tells us the concentration of the metal ion.
Iron (III) Fe3+ions precipitates
Brown
Copper (II) Cu2+ ion precipitates
blue
Iron (II) Fe2+ ion precipitates
Green
Magnesium Mg2+ ion precipitates
White
Calcium, Ca2+ ion precipitates
White
Aluminium Al3+ precipitate
White
How to distinguish between Aluminium ions from calcium ions and magnesium ions.
Add extra sodium hydroxide the aluminum hydroxide eventually will become colorless
If extra sodium hydroxide is added to calcium and magnesium the solution will not change.
What is a formulation
A mixture that has been designed as a useful product
Step 1 of testing for a Carbonate ion
Add dilute acid
What will happen once Carbonate reacts with dilute acid
Carbon dioxide produced/created
Will see effervescence
Chloride ions produce what precipitate. + colour
White precipitate of silver chloride
Bromide ions produce what precipitate + colour
Cream precipitate of silver bromide.
Iodide ions produce what precipitate + colour
Yellow precipitate of silver iodide
What is the formula for the aqueous solution of lime water
calcium hydroxide
How to test for carbon dioxide (5)
+ positive result
We test for co2 using limewater (lime water is an aqueous solution of calcium hydroxide)
Draw some of the gas in the test tube containing the possible co2 into a plastic pipette
We then bubble the gas through the limewater
Repeat several times
Positive result = lime water turns cloudy
Negative result = nothing happens