Chemical Analysis Flashcards

1
Q

What is a pure substance?

A

Single element or compound not mixed with any other substance which melt and boil at specific temperatures

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2
Q

What is an impure substance?

A

Contains more than one element or compound in a mixture.
Melts and boils at a range of temperatures

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3
Q

What are formulations?

A

Examples of mixtures which have many different components in very specific proportions to make them useful as fuel, cleaning agents, paints, alloys, fertilisers and foods

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4
Q

What is the mobile phase?

A

The solvent which must be below the pencil line or the substances will be dissolved away from the paper

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5
Q

What does it mean if the substance travels a long way up the paper?

A

It is more soluble

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6
Q

What does it mean if the substance only produces one spot?

A

The substance is pure

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7
Q

What is the solvent front?

A

The top of where the solvent travels to up the paper

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8
Q

What is the stationary phase?

A

The paper

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9
Q

What is chromatography?

A

A method to separate different components in a mixture

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10
Q

What is the Rf value?

A

Distance moved by substance divided by distance moved by solvent

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11
Q

How do you test for cations?

A

Sodium hydroxide solution is added to the substance

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12
Q

Positive test for Al3+

A

White precipitate which dissolves in excess of

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13
Q

Positive test for Ca2+

A

White precipitate does not dissolve

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14
Q

Positive test for Mg2+

A

White precipitate does not dissolve

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15
Q

Positive test for Cu2+

A

Blue precipitate

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16
Q

Positive test for Fe2+

A

Green precipitate

17
Q

Positive test for Fe3+

A

Brown precipitate

18
Q

How do you test for a carbonate CO3 2-?

A

Add dilute (hydrochloric) acid and test with limewater

19
Q

How do you test for sulfates?

A

Add barium chloride solution in the presence of hydrochloric acid and you should see a white precipitate form

20
Q

How do you test for halide ions?

A

Silver nitrate solution and nitric acid

21
Q

Positive test for Cl-

A

White precipitate

22
Q

Positive test for I-

A

Yellow precipitate

23
Q

Positive test for Br-

A

Cream precipitate

24
Q

Why does a flame test not work if there is more than one metal in the substance?

A

The colours mix and intense colours mask more subtle colours

25
Q

Lithium flame colour

A

Crimson

26
Q

Sodium flame colour

A

Yellow

27
Q

Potassium flame colour

A

Lilac

28
Q

Calcium flame colour

A

Orange red

29
Q

Copper flame colour

A

Green

30
Q

What is instrumental analysis?

A

Involves complex scientific equipment to test substances
Rapid
Accurate
Sensitive

31
Q

What is flame emission spectroscopy?

A

Instrumental method to test for metal ions
Sample solution is put into flame and the light given off is passed through a spectroscope
The instrument tells you the exact wavelength of light being given off as a line spectrum
Compare spectrum to reference
You can also measure concentration of substance